CHEMISTRY GLOSSARY

molar enthalpy of melting    →   molarna entalpija taljenja

Molar enthalpy of melting (Δ_s ^lH) is a change of enthalpy during melting divided by the molarity of a solid matter, and is equal to the energy used when melting is conducted under constant pressure.

molar enthalpy of evaporation    →   molarna entalpija isparavanja

Molar enthalpy of evaporation (Δ_l ^gH) is a change of enthalpy during evaporation divided by molarity of a liquid, and is equal to the heat energy spent when the evaporation is conducted under constant pressure, Δ_l ^gH=Q.

heat of fusion    →   toplina taljenja

Heat of fusion or enthalpy of fusion is the heat required to convert a substance from the solid to the liquid state with no temperature change (also called latent heat of fusion or melting).

molar quantity    →   molarna veličina

Molar quantity is often convenient to express an extensive quantity (e.g., volume, enthalpy, heat capacity, etc.) as the actual value divided by the amount of substance (number of moles). The resulting quantity is called molar volume, molar enthalpy, etc.

enthalpy    →   entalpija

Enthalpy (H) is a thermodynamic property of a system defined by

where U is the internal energy of the system, p its pressure, and V its volume. J.W. Gibbs put the concept of an ensemble forward in 1902. In a chemical reaction carried out in the atmosphere the pressure remains constant and the enthalpy of reaction (ΔH), is equal to

For an exothermic reaction ΔH is taken to be negative.

molar mass    →   molarna masa

Molar mass is the mass of one mole of a substance.

It is normally expressed in units of g mol^-1, in which case its numerical value is identical with the relative molecular mass.

molar    →   molarna

Denoting that an extensive physical property is being expressed per amount of substance, usually per mole.

molar concentration    →   molarna koncentracija

See Amount concentration

enthalpy growth    →   prirast entalpije

Enthalpy growth (ΔH) is that part of energy of system which can be translated into heat (Q) with a permanent pressure.

melting    →   taljenje

Melting happens when a solid turns into a liquid, most often caused by warming of a solid. An example is ice turning into water. Melting is not the same as dissolving.