CHEMISTRY GLOSSARY

molar absorption coefficient    →   molarni apsorpcijski koeficijent

Molar absorption coefficient (ε) is the absorption coefficient divided by amount-of-substance concentration of the absorbing material in the sample solution (ε = a/c). The SI unit is m²mol^-1. Also called extinction coefficient, but usually in units of dm³cm^-1mol^-1.

molar volume    →   molarni volumen

Molar volume is the volume occupied by substance per unit amount of substance. The volume of the gas at 0 °C and 101 325 Pa is 22.4 dm³mol^-1.

heat of vaporisation    →   toplina isparavanja

Heat of vaporisation or enthalpy of vaporisation is the heat required to convert a substance from the liquid to the gaseous state with no temperature change (also called latent heat of vaporization).

van’t Hoff equation    →   van Hoffova jednadžba

Van’t Hoff equation is the equation expressing the temperature dependence on the equilibrium constant K of a chemical reaction:

where Δ_rH° is the standard enthalpy of reaction, R the molar gas constant, and T the temperature.

molar fraction    →   molarni udio

See Amount fraction

absorbance    →   apsorbancija

Absorbance (A) is a logarithm of the ratio of incident radiant power (P_o) to transmitted radiant power (P) through a sample (excluding the effects on cell walls).

The absorption of light by a substance in a solution can be described mathematically by the Beer-Lambert law

where A is the absorbance at a given wavelength of light, ε is the molar absorbtivity or extinction coefficient (L mol^-1 cm^-1), unique to each molecule and varying with wavelength, b is the length of light path through the sample (cm), and c is the concentration of the compound in solution (mol L^-1).

antimony    →   antimon

Antimony has been known since ancient times. The origin of the name comes from the Latin word stibium meaning mineral stibnite. It is hard, brittle, silvery-white semimetal. Stable in dry air. Toxic by ingestion or inhalation. Antimony is found in stibnite (Sb₂S₃) and in valentinite (Sb₂O₃). It is alloyed with other metals to increase their hardness. Also in the manufacture of a few special types of semiconductor devices. Also in plastics and chemicals. A few kinds of over-the-counter cold and flu remedies use antimony compounds.

Beer’s law    →   Beerov zakon

Beer’s law (or Beer-Lambert law) is the functional relationship between the quantity measured in an absorption method (A) and the quantity sought, the analyte concentration (c). As a consequence of interactions between the photons and absorbing particles, the power of the beam is attenuated from P_o to P. Beer’s law can be written

where A is the absorbance at a given wavelength of light, ε is the molar absorbtivity or extinction coefficient (L mol^-1 cm^-1), unique to each molecule and varying with wavelength, b is the length of light path through the sample (cm), and c is the concentration of the compound in solution (mol L^-1).

ceramics    →   keramika

Ceramics are an inorganic material of a very high melting point. Ceramics are metal silicates, oxides, nitrides, etc.

decomposing    →   raščinjavanje

Decomposing in analytical chemistry means that a certain substance is converted, by melting it with a suitable melting medium (sodium carbonate, sodium hydroxide, sodium peroxide, ...) in the kind of compound which will afterwards that dissolve in water, acid or base very easily.