CHEMISTRY GLOSSARY

Beer’s law    →   Beerov zakon

Beer’s law (or Beer-Lambert law) is the functional relationship between the quantity measured in an absorption method (A) and the quantity sought, the analyte concentration (c). As a consequence of interactions between the photons and absorbing particles, the power of the beam is attenuated from P_o to P. Beer’s law can be written

where A is the absorbance at a given wavelength of light, ε is the molar absorbtivity or extinction coefficient (L mol^-1 cm^-1), unique to each molecule and varying with wavelength, b is the length of light path through the sample (cm), and c is the concentration of the compound in solution (mol L^-1).

beryllium    →   berilij

Beryllium was discovered by Friedrich Wöhler (Germany) and independently by A. B. Bussy (France) in 1828. The origin of the name comes from the Greek word beryllos meaning mineral beryl; also called glucinium from the Greek word glykys meaning sweet. It is steel-grey metal. It resists attack by concentrated nitric acid, has excellent thermal conductivity and is nonmagnetic. At ordinary temperatures, it resists oxidation in air. Beryllium and its salts are toxic and should be handled with the greatest of care. Beryllium is found mostly in minerals like beryl [AlBe₃(Si₆O₁₈)] and chrysoberyl (Al₂BeO₄). Pure beryllium is obtained by chemically reducing beryl mineral. Also by electrolysis of beryllium chloride. Its ability to absorb large amounts of heat makes it useful in spacecraft, missiles, aircraft, etc. Emeralds are beryl crystals with chromium traces giving them their green colour.

Bragg angle    →   Braggov kut

Bragg angle (Θ) is the angle between an incident X-ray beam and a set of crystal planes for which the secondary radiation displays maximum intensity as a result of constructive interference. British physicist Sir William Henry Bragg and his son Sir William Lawrence Bragg developed a simple relation for scattering angles, now call Bragg’s law.

which relates the angle θ between a crystal plane and the diffracted X-ray beam, the wavelength λ of the x-rays, the crystal plane spacing d, and the diffraction order n (any integer).

The diffraction experiment as presently considered is intended to provide quantitative information on the lattice constant and shape characteristics of the unit cell.

calomel electrode    →   kalomel elektroda

Calomel electrode is a type of half cell in which the electrode is mercury coated with calomel (Hg₂Cl₂) and the electrolyte is a solution of potassium chloride and saturated calomel. In the calomel half cell the overall reaction is

Table: Dependence of potential of calomel electrode upon temperature and concentration of KCl according to standard hydrogen electrode

Carnot cycle    →   Carnotov kružni proces

Carnot cycle is the most efficient cycle of operations for a reversible heat engine. Published in 1824 by French physicist Nicolas Léonard Sadi Carnot (1796-1832), it consists of four operations on the working substance in the engine:

1-2: Isothermal expansion at thermodynamic temperature T₁ with heat Q_H taken in.

2-3: Adiabatic expansion with a fall of temperature to T₂.

3-4: Isothermal compression at temperature T₂ with heat Q_C given out.

4-1: Adiabatic compression at temperature back to T₁.

According to the Carnot principle, the efficiency of any reversible heat engine depends only on the temperature range through which it works, rather than the properties of the working substances.

chemical balance    →   kemijska ravnoteža

Chemical balance is a degree of reversible reaction in a closed system, when the forward and backward reaction happen at same rates and their effects annul each other, while the concentration of reactants and products stays the same.

coagulation    →   koaguliranje

Coagulation is a process of colloid particles merging into bigger ones. By removing the charge form a colloid ion, by increasing the temperature or by increasing electrolyte concentration, colloid particles will gather into bigger groups precipitate will emerge. Precipitate that is formed in this way (coagulate) is amorphic and considerably polluted with adsorbed pollutants.

collision theory    →   teorija sudara

Collision theory is theory that explains how chemical reactions take place and why rates of reaction alter. For a reaction to occur the reactant particles must collide. Only a certain fraction of the total collisions cause chemical change; these are called successful collisions. The successful collisions have sufficient energy (activation energy) at the moment of impact to break the existing bonds and form new bonds, resulting in the products of the reaction. Increasing the concentration of the reactants and raising the temperature bring about more collisions and therefore more successful collisions, increasing the rate of reaction.

colorimetry    →   kolorimetrija

Colorimetry is a quantitative chemical analysis by colour using a colorimeter.

concentrated solution    →   koncentrirana otopina

Concentrated solution is a solution that contains a large amount of solute relative to the amount that could dissolve.