Calomel electrode is a type of half cell in which the electrode is mercury coated with calomel (Hg2Cl2) and the electrolyte is a solution of potassium chloride and saturated calomel. In the calomel half cell the overall reaction is
Table: Dependence of potential of calomel electrode upon temperature and concentration of KCl according to standard hydrogen electrode
Potential vs. SHE / V | |||
---|---|---|---|
t / °C | 0.1 mol dm-3 | 3.5 mol dm-3 | sat. solution |
15 | 0.3362 | 0.254 | 0.2511 |
20 | 0.3359 | 0.252 | 0.2479 |
25 | 0.3356 | 0.250 | 0.2444 |
30 | 0.3351 | 0.248 | 0.2411 |
35 | 0.3344 | 0.246 | 0.2376 |
Enthalpy growth (ΔH) is that part of energy of system which can be translated into heat (Q) with a permanent pressure.
Environment (in thermodynamics) is the whole universe, except the system that is being observed.
Equation of state is an equation relating the pressure, volume, and temperature of a substance or system. Equation of state for ideal gas
where p is pressure, V molar volume, T temperature, and R the molar gas constant (8.314 JK-1mol-1).
Carbohydrates (often called carbs for short) are polyhydroxy aldehydes or ketones, or substances that yield such compounds on hydrolysis. They are also known as saccharides, a term derived from the Latin word saccharum for sugar. Carbohydrates are the most abundant class of compounds in the biological world, making up more than 50 % of the dry weight of the Earth’s biomass. Every type of food we eat can have its energy traced back to a plant. Plants use carbon dioxide and water to make glucose, a simple sugar, in photosynthesis. Other carbohydrates such as cellulose and starch are made from the glucose. Light from the sun is absorbed by chlorophyll and this is converted to the energy necessary to biosynthesize carbohydrates
The term carbohydrate was applied originally to monosaccharides, in recognition of the fact that their empirical composition can be expressed as Cx(H2O)y. Later structural studies revealed that these compounds were not hydrates but the term carbohydrate persists.
Carbohydrates are generally classed as either simple or complex. Simple sugars, or monosaccharides, are carbohydrates that can’t be converted into smaller subunits by hydrolysis. Complex carbohydrates are made of two (disaccharides) or more (oligosaccharides, polysaccharides) simple sugars linked together by acetal (glycosidic) bonds and can be split into the former by hydrolysis.
Eequivalence point is the point in a titration when enough titrant has been added to react completely with the analyte.
Eutectic is a solid solution consisting of two or more substances and having the lowest freezing point of any possible mixture of these components.
Eutectic point is the lowest temperature at which the eutectic mixture can exist in a liquid phase. A liquid having the eutectic composition will freeze at a single temperature without a change of composition.
Evaporation is the change of state of a liquid into a vapour at a temperature below the boiling point of the liquid.
Faradaic reaction is a heterogeneous charge-transfer reaction occurring at the surface of an electrode.
Generalic, Eni. "Ledište." Croatian-English Chemistry Dictionary & Glossary. 29 June 2022. KTF-Split. {Date of access}. <https://glossary.periodni.com>.
Glossary
Periodic Table