CHEMISTRY GLOSSARY

allotropy    →   alotropija

Allotropy (Gr. allos, other, and tropos, manner) is the phenomenon of an element existing in two or more physical forms in the same physical state. The difference between the forms involves either crystaline structure (white, red and black phosphorus), the number of atoms in the molecule of a gas (diatomic oxygen and triatomic ozone), or the molecular structure of a liquid (liquid helium an helium II).

In some cases, the allotropes are stable over a temperature range, with a definite transition point at which one changes into the other. For instance, tin has two allotropes: white (metallic) tin stable above 13.2 °C and grey (nonmetallic) tin stable below 13.2 °C. This form allotropy is called enantiotropy. Form of allotropy, in which there is no transition temperature at which the two are in equilibrium, is called monotropy.

Allotropy does not apply to the substance existing in different physical states as, for example, when ice melts and changes from solid ice to liquid water.

Allotropy is generally restricted to describing polymorphic behaviour in elements, while polymorphism may refer to any material having multiple crystal structures.

barrier film    →   barijerni film

Barrier film is a thin, continuous, non-porous, electrically insulating film on metal surfaces (usually comprised of oxides).

alpaca    →   alpaka

Alpaca (alpaka) or Nickel Silver is the generic name for any of a range of non-precious bright silvery-grey metal alloys, composed of copper, nickel and zinc. Despite its name it contains no real silver. It is also commonly called German Silver.

There are many different formulations of alloys which fall within the general term of Nickel Silver. All contain copper, nickel and zinc, while some formulations may additionally include antimony, tin, lead or cadmium. A representative formulation is 65 % copper, 18 % nickel, 17 % zinc. Nickel Silver is widely used for the commercial production of industrial components, housewares, flatware and cutlery, and as the metal substrate for silver-plated goods.

amount fraction    →   količinski udio

Amount fraction, x_A, (y for gaseous mixtures) is the ratio of the amount of substance (number of moles) of substance A to the total amount of substance in a mixture.

ampere    →   amper

Ampere (A) is the SI base unit of electric current.

The ampere is that constant current which, if maintained in two straight parallel conductors of infinite length, of negligible circular cross-section, and placed 1 metre apart in vacuum, would produce between these conductors a force equal to 2×10^-7 newton per metre of length.

angular acceleration    →   kutna akceleracija

If the angular velocity of a body changes from an initial value ω_i to a final value ω_f, average angular acceleration, α, can be defined for the time interval Δt = t_f - t_i:

The instantaneous angular acceleration, α, is the limit of the average angular acceleration, as Δt is made to approach zero:

SI unit for angular acceleration is s^-2.

bathymetry    →   batimetrija

Bathymetry (from the Greek word bathus, deep) is the science of measuring the depths of the oceans, seas, lakes, etc. or the topographic maps of the sea floor that result from such measurements. Bathymetric charts are designed to present accurate, measurable description and visual presentation of the submerged terrain.

bcc    →   bcc

bcc is abbreviation for body-centered cubic lattice.

analytical balance    →   analitička vaga

Analytical balances are instruments used for precise determining mass of matter. Analytical balances are sensitive and expensive instruments, and upon their accuracy and precision the accuracy of analysis result depends. The most widely used type of analytical balances are balances with a capacity of 100 g and a sensitivity of 0.1 mg. Not one quantitative chemical analysis is possible without usage of balances, because, regardless of which analytical method is being used, there is always a need for weighing a sample for analysis and the necessary quantity of reagents for solution preparation.

The working part of the balance is enclosed in a glass-fitted case. The baseplate is usually of black glass or black slate. The beam has agate knife-edges at its extremes, supporting stirrups from which balance pans are suspended. Another agate or steel knife-edge is fixed exactly in the middle of the beam on its bottom side. This knife-edge faces downwards and supports the beam. When not in use and during loading or unloading of the pans, the balance should be arrested.

The principle of operation of a modern laboratory balance bears some resemblance to its predecessor - the equal arm balance. The older instrument opposed the torque exerted by an unknown mass on one side of a pivot to that of an adjustable known weight on the other side. When the pointer returned to the center position, the torques must be equal, and the weight was determined by the position of the moving weights.

Modern electronic laboratory balances work on the principle of magnetic force restoration. In this system, the force exerted by the object being weighed is lifted by an electromagnet. A detector measures the current required to oppose the downward motion of the weight in the magnetic field.

antimony    →   antimon

Antimony has been known since ancient times. The origin of the name comes from the Latin word stibium meaning mineral stibnite. It is hard, brittle, silvery-white semimetal. Stable in dry air. Toxic by ingestion or inhalation. Antimony is found in stibnite (Sb₂S₃) and in valentinite (Sb₂O₃). It is alloyed with other metals to increase their hardness. Also in the manufacture of a few special types of semiconductor devices. Also in plastics and chemicals. A few kinds of over-the-counter cold and flu remedies use antimony compounds.