CHEMISTRY GLOSSARY

gold    →   zlato

Gold has been known since ancient times. The origin of the name comes from the Latin word aurum meaning gold. It is soft, malleable, bright yellow metal. Unaffected by air, water, alkalis and most acids. Gold is found in veins in the crust, with copper ore and native. Used in electronics, jewellery and coins. It is a good reflector of infrared radiation, so a thin film of gold is applied to the glass of skyscrapers to reduce internal heating from sunlight.

haematite    →   hematit

Haematite is a mineral of iron(III) oxide Fe₂O₃. It is the most important ore of iron and usually occurs in two main forms: as a massive red kidney-shaped ore and as grey to black metallic crystals known as specular iron ore. Haematite is the major red colouring agent in rocks; the largest deposits are of sedimentary origin. In industry haematite is also used as a polishing agent (jeweller’s rouge) and in paints.

hafnium    →   hafnij

Hafnium was discovered by Dirk Coster (Denmark) and Georg Karl von Hevesy (Hungary) in 1923. The origin of the name comes from the Latin name Hafnia meaning Copenhagen. It is silvery, ductile metal. Exposed surfaces form oxide film. Resists alkalis and acids (except HF). Toxic. Metal ignites and burns readily. Hafnium is obtained from mineral zircon or baddeleyite. Used in reactor control rods because of its ability to absorb neutrons.

histidine    →   histidin

Histidine is an electrically charged amino acids with basic side chains. It is an essential amino acid, which means that humans cannot synthesize it, so it must be ingested. Histidine is perhaps the most common and versatile catalytic residue in proteins. The imidazole sidechain of histidine has a pKa of approximately 6.0. This means that, at physiologically relevant pH values, relatively small shifts in pH will change its average charge. The unprotonated imidazole is nucleophilic and can serve as a general base, while the protonated form can serve as a general acid. In addition, it is often a ligand for transition metal ions such as iron and zinc.

• Abbreviations: His, H
• IUPAC name: 2-amino-3-(1H-imidazol-5-yl)propanoic acid
• Molecular formula: C₆H₉N₃O₂
• Molecular weight: 155.15 g/mol

Zimmermann-Reinhardt’s reagent    →   Zimmermann-Reinhardtov reagens

Zimmermann-Reinhardt’s reagent is a mixture of manganese(II) sulphate, sulphuric acid and phosphorus acid. It is used for preventing oxidation of chloride ion while titrating iron(II) ion with permanganate solution.

holmium    →   holmij

Holmium was discovered by Per Theodore Cleve (Sweden) in 1879. The origin of the name comes from the Greek word Holmia meaning Stockholm. It is fairly soft, malleable, lustrous, silvery metal. Reacts slowly with oxygen and water. Dissolves in acids. Can react violently with air or halogens. Holmium occurs in gadolinite. Most often from monazite sand. It has very few practical applications; however, it has some unusual magnetic properties that offer some hope for future applications.

hydrogen    →   vodik

Hydrogen was discovered by Sir Henry Cavendish (England) in 1766. The origin of the name comes from the Greek words hydro and genes meaning water and generate. It is colourless, odourless gas, burns and forms explosive mixtures in air. Reacts violently with oxidants. Hydrogen is the most abundant element in the universe. Commercial quantities of hydrogen are produced by reacting superheated steam with methane or carbon. In lab work from reaction of metals with acid solutions or electrolysis. Most hydrogen is used in the production of ammonia and in metal refining. Also used as fuel in rockets. Its two heavier isotopes (deuterium and tritium) used respectively for nuclear fusion.

hydrolysis    →   hidroliza

Hydrolysis is a chemical reaction in which water reacts with another substance to form two or more new substances. This involves ionisation of the water molecule, as well as splitting of the compound hydrolysed, e.g.

Examples are conversion of starch to glucose by water in the presence of suitable catalysts and a reaction of the ions of a dissolved salt to form various products, such as acids, complex ions, etc.

indium    →   indij

Indium was discovered by Ferdinand Reich and Hieronymus Theodor Richter (Germany) in 1863. Named after the indicum (colour indigo), the colour it shows in a spectroscope. It is rare, very soft, silver-white metal. Stable in air and water. Dissolves in acids. Metal can ignite and burn. Indium is found in certain zinc ores. Used to coat high speed bearings and as an alloy that lowers the melting point of other metals. Relatively small amounts are used in dental items and in electronic semiconductors.

invert sugar    →   invertni šećer

Invert sugar is a mixture of equal parts of glucose and fructose resulting from the hydrolysis of sucrose (saccharose). The name stemming from the fact that it rotates of plane polarized light in the opposite direction of sucrose. Sucrose is dextrorotatory - it rotates polarized light clockwise ([α]_D = +66.5°). Invert sugar rotates the plane of the polarized light counterclockwise ([α]_D = -22°) due to the strongly levorotatory nature of fructose ([α]_D = -92°).

Homemade artificial honey (invert sugar syrup): Dissolve two parts of household sugar (1 kg) with stirring in one part of water (0.5 kg) in a saucepan over low heat. Add 1 g of citric acid or the juice of one lemon to the mixture. Bring the ingredients to a slow boil. It can take anywhere between 15 minutes to 1 hour. The end result is sticky, golden syrup. Let it sit at room temperature until it is cool.