CHEMISTRY GLOSSARY

acid rain    →   kisela kiša

Acid rain is rainwater that shows acid reaction because of nitrogen and sulphur oxides absorption. It is generated mainly by industrial pollutions.

acid salt    →   kisela sol

Acid salt is a compound formed by replacing hydrogen in an acid with a metal (or a radical that acts like a metal).

acid dissociation constant    →   konstanta disocijacije kiseline

Acid dissociation constant (K_a) is the equilibrium constant for the dissociation of an acid HA through the reaction

The quantity pK_a = -log K_a is often used to express the acid dissociation constant.

acid halide    →   kiselinski halogenid

Acid halide is organic compound containing the group -COX where X is a halogen atom.

acid radical    →   kiseli radikal

Acid radical is an anion left after removal of hydrogen atoms from an acid.

acid-base indicator    →   kiselo-bazni indikator

Acid-base indicator is a weak acid or weak base, such as litmus, methyl orange or phenolphthalein, which changes colour when it gains or loses an H⁺ ion.

acrylic acid    →   akrilna kiselina

Acrylic acid (propenoic acid) is a colourless liquid, smelling like acetic acid. It can be formed by acrolein oxidation. It readily polymerizes and is used in the manufacture of acrylic resins, transparent plastic materials (organic glass).

acid    →   kiselina

Acid is a type of compound that contains hydrogen and dissociates in water to produce positive hydrogen ions. The reaction for an acid HA is commonly written:

In fact, the hydrogen ion (the proton) is solvated, and the complete reaction is:

This definition of acids comes from the Arrhenius theory. Such acids tend to be corrosive substances with a sharp taste, which turn litmus red and produce colour changes with other indicators. They are referred to as protonic acids and are classified into strong acids, which are almost completely dissociated in water, (e.g. sulphuric acid and hydrochloric acid), and weak acids, which are only partially dissociated (e.g. acetic acid and hydrogen sulphide). The strength of an acid depends on the extent to which it dissociates, and is measured by its dissociation constant.

In the Lowry-Brønsted theory of acids and bases (1923), the definition was extended to one in which an acid is a proton donor (a Brønsted acid), and a base is a proton acceptor (a Brønsted base). An important feature of the Lowry-Brønsted concept is that when an acid gives up a proton, a conjugate base is formed that is capable of accepting a proton.

Similarly, every base produces its conjugate acid as a result of accepting a proton.

For example, acetate ion is the conjugate base of acetic acid, and ammonium ion is the conjugate acid of ammonia.

As the acid of a conjugate acid/base pair becomes weaker, its conjugate base becomes stronger and vice versa.

A further extension of the idea of acids and bases was made in the Lewis theory. In this, a G. N. Lewis acid is a compound or atom that can accept a pair of electrons and a Lewis base is one that can donate an electron pair. This definition encompasses "traditional" acid-base reactions, but it also includes reactions that do not involve ions, e.g.

in which NH₃ is the base (donor) and BCl₃ the acid (acceptor).

acid-base titration    →   kiselo-bazna titracija

Acid-base titration is an analytical technique in volumetric analysis, where an acid of known concentration is used to neutralise a known volume of a base, and the observed volume of the acid required is used to determine the unknown concentration of the base. An acid-base indicator is used to determine the end-point of the titration.

battery acid    →   baterijska kiselina

Battery acid is a solution of approximately 6 mol L^-1 sulphuric acid used in the lead storage battery