CHEMISTRY GLOSSARY

complex    →   kompleks

Complex or coordination compound is formed when metal ion (central ion) reacts with molecules or ions which have free electron pairs (ligand). Metal ion and ligand are bonded with a polar covalent bond in which both electrons are given by the ligand.

computational chemistry    →   kompjutacijska kemija

Computational chemistry is a branch of chemistry concerned with the prediction or simulation of chemical properties, structures, or processes using numerical techniques.

condensational polymerisation    →   kondenzacijska polimerizacija

Condensational polymerisation is a reaction of polymerisation in which monomers together create a polymer by losing small molecules like water.

congener    →   srodnost

Congener is a term in chemistry that refers to one of many variants or configurations of a common chemical structure. Elements belonging to the same group on the periodic table. For example, sodium and potassium are congeners.

cosmic rays    →   kozmičke zrake

Cosmic rays are high energy (10¹⁵ eV- 10¹⁷ eV) nuclear particles, electrons, and photons, originating mostly outside the solar system, which continually bombard the Earth’s atmosphere.

blast furnace    →   visoka peć

Blast furnace is a furnace for smelting of iron from iron oxide ores (hematite, Fe₂O₃ or magnetite, Fe₃O₄). Coke, limestone and iron ore are poured in the top, which would normally burn only on the surface. The hot air blast to the furnace burns the coke and maintains the very high temperatures that are needed to reduce the ore to iron. The reaction between air and the fuel generates carbon monoxide. This gas reduces the iron(III) oxide in the ore to iron.

Because the furnace temperature is in the region of 1500 °C, the metal is produced in a molten state and this runs down to the base of the furnace.

The production of iron in a blast furnace is a continuous process. The furnace is heated constantly and is re-charged with raw materials from the top while it is being tapped from the bottom. Iron making in the furnace usually continues for about ten years before the furnace linings have to be renewed.

boron    →   bor

Boron compounds have been known for thousands of years, but the element was not discovered until 1808 by Sir Humphry Davy (England) and independently by Joseph-Louis Gay-Lussac (France) and L. J. Thenard (France). The origin of the name comes from the Arabic word buraq and the Persian word burah meaning boraks. It is hard, brittle, lustrous black semimetal. Unreactive with oxygen, water, alkalis or acids. Combines with most metals to form borides. Boron is obtained from kernite, a kind of borax (Na₂B₄O₇·10H₂O). High purity boron is produced by electrolysis of molten potassium fluroborate and potassium chloride (KCl). Amorphous boron is used in pyrotechnic flares to provide a distinctive green color and in rockets as an igniter.

Butler-Volmer equation    →   Butler-Volmerova jednadžba

Butler-Volmer equation is an activation controlled reaction, the one for which the rate of reaction is controlled solely by the rate of the electrochemical charge transfer process, which is in turn an activation-controlled process. This gives rise to kinetics that are described by the Butler-Volmer equation:

where i_o is exchange current density, η is overpotential (η = E - E_o), n is number of electrons, α_A is anodic transfer coefficient, and α_C is cathodic transfer coefficient

critical mass    →   kritična masa

Critical mass is the minimum mass of a fissionable material (²³⁵U or ²³⁹Pu) that will initiate an uncontrolled chain reaction as in an atomic bomb. The critical mass of pure ²³⁹Pu is about 4.5 kg, and of ²³⁵U about 15 kg.

cyanogen    →   cijan

Cyanogen is a colourless gas, (CN)₂ with a pungent odour. The compound is very toxic. It my be prepared in the laboratory by heating mercury (II) cyanide.