CHEMISTRY GLOSSARY

base    →   baza

Historically, base is a substance that yields an OH - ion when it dissociates in solution, resulting in a pH>7. In the Brønsted definition, a base is a substance capable of accepting a proton in any type of reaction. The more general definition, due to G.N. Lewis, classifies any chemical species capable of donating an electron pair as a base. Typically, bases are metal oxides, hydroxides, or compounds (such as ammonia) that give hydroxide ions in aqueous solution.

battery    →   baterija

Battery a device that converts chemical energy to electrical energy. The process underlying the operation of a battery involves a chemical reaction in which electrons are transferred from one chemical species to another. This process is carried out in two half-reactions, one that involves the loss of electrons and one that involves their gain. The battery is an electrochemical cell divided in two half-cells, and reaction proceeds when these are connected together by an electrically conducting pathway. The passage of electrons from one half-cell to the other corresponds to an electric current. Each half-cell contains an electrode in contact with the reacting species. The electrode which passes electrons into the circuit when battery discharges is called anode and is negative terminal. The electrode which receives electrons is called cathode, and is the battery’s positive terminal. The electrical circuit is completed by an electrolyte, an electrically conducting substance placed between the two electrodes which carriers a flow of charge between them. In wet cells, the electrolyte is a liquid containing dissolved ions, whose motion generates an electrical current; in dry cells the electrolyte is basely solid, for example, a solid with mobile ions or porous solid saturated with an ionic solution.

Born-Haber cycle    →   Born-Haberov kružni proces

Born-Haber cycle is a cycle of reactions used for calculating the lattice energies of ionic crystalline solids. For a compound MX, the lattice energy is the enthalpy of the reaction

The standard enthalpy of formation of the ionic solid is the enthalpy of the reaction

The cycle involves equating this enthalpy (which can be measured) to the sum of the enthalpies of a number of steps proceeding from the elements to the ionic solid. The steps are:

1) Atomization of the metal

2) Atomization of the nonmetal

3) Ionisation of the metal

This is obtained from the ionisation potential.

4) Ionisation of the nonmetal

This is electron affinity.

5) Formation of the ionic solids

Equation of the enthalpies gives

from which ΔH_L can be found.

boron    →   bor

Boron compounds have been known for thousands of years, but the element was not discovered until 1808 by Sir Humphry Davy (England) and independently by Joseph-Louis Gay-Lussac (France) and L. J. Thenard (France). The origin of the name comes from the Arabic word buraq and the Persian word burah meaning boraks. It is hard, brittle, lustrous black semimetal. Unreactive with oxygen, water, alkalis or acids. Combines with most metals to form borides. Boron is obtained from kernite, a kind of borax (Na₂B₄O₇·10H₂O). High purity boron is produced by electrolysis of molten potassium fluroborate and potassium chloride (KCl). Amorphous boron is used in pyrotechnic flares to provide a distinctive green color and in rockets as an igniter.

brass    →   mjed

Brasses are alloys of copper and zinc (generally 5 % to 40 %). Brass has been known to man since prehistoric times, long before zinc itself was discovered. It was produced by melting copper together with calamine, a zinc ore. Its ductility reaches a maximum with about 30 % zinc and its tensile strength with 45 % although this property varies greatly with the mechanical and heat treatment of the alloy. Typical applications included gears, plumbing ware fittings, adapters, valves and screw machine products. The French horn is a valved brass wind instrument.

Brass may contain small amounts of other alloying elements, such as aluminum, lead, tin, or nickel. Lead can be added as an alloying element resulting in a brass that can be rapidly machined and produces minimal tool wear. Additions of aluminium, iron and manganese to brass improve strength, whilst silicon additions improve wear resistance. Brass containing tin (< 2 % ) is less liable to corrosion in seawater; it is sometimes called naval brass and is used in naval construction.

bronze    →   bronca

Bronze is an alloy made primarily of copper and tin. It may contain as much as 25 % tin. Bronzes with 10 % or more tin are harder, stronger, and resistant to corrosion. As bronze weathers, a brown or green film forms on the surface. This film inhibits corrosion. Silicon or aluminium is often added to bronze to improve resistance to corrosion. Phosphorus, lead, zinc, and other metals may be added for special purposes. The alloy is hard and easily cast and is extensively used in bearings, valves and other machine parts.

Bronze was one of the first alloys developed by ancient metal workers. The Bronze Age occurred in Europe around 2200 to 700 BC. Bronze was used for weapons such as spearheads, swords, and knives. Since ancient times, bronze has been the most popular metal for casting statues and other art objects.

The term bronze has been adopted commercially for many copper-rich alloys that contain little or no tin but are similar in colour to bronze, including aluminium bronze, manganese bronze, and silicon bronze. Aluminium bronze is used to make tools and, because it will not spark when struck. Manganese bronze is actually a brass that contains manganese. It is often used to make ship propellers because it is strong and resists corrosion by sea water.

chemiluminescence    →   kemiluminiscencija

Chemiluminescence is energy release in form of electromagnetic radiation during a chemical reaction.

chemisorption    →   kemisorpcija

Chemisorption is a binding of a liquid or gas on the surface or in the interior of a solid by chemical bonds or forces.

chemotherapy    →   kemoterapija

Chemotherapy is the treatment of disease by means of chemicals that have a specific toxic effect upon the disease producing microorganisms (antibiotics) or that selectively destroy cancerous tissue (anticancer therapy).

computational chemistry    →   kompjutacijska kemija

Computational chemistry is a branch of chemistry concerned with the prediction or simulation of chemical properties, structures, or processes using numerical techniques.