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Insulator is a material in which the highest occupied energy band (valence band) is completely filled with electrons, while the next higher band (conduction band) is empty. Solids with an energy gap of 5 eV or more are generally considered as insulators at room temperature. Their conductivity is less than 10-6 S/m and increases with temperature.
Allotropes are the elements which exist in two or more different forms in the same physical state. Allotropes generally differ in physical properties and may also differ in chemical activity.
Diamond, graphite and fullerenes are three allotropes of the element carbon. Graphite is a soft, black, slippery substance; by contrast, diamond is one of the hardest substances known. The different properties of the allotropes arise from their chemical structures. Diamonds typically crystallize in the cubic crystal system and consist of tetrahedrally bonded carbon atoms. Graphite crystallizes in the hexagonal system. In the fullerenes, the carbon atoms taking the form of a hollow sphere, ellipsoid, or tube.
In some cases, the allotropes are stable over a temperature range, with a definite transition point at which one changes into the other. For instance, tin has two allotropes: white (metallic) tin stable above 13.2 °C and grey (nonmetallic) tin stable below 13.2 °C.
The term allotropes may also be used to refer to the molecular forms of an element. Ozone is a chemically active triatomic allotrope of the element oxygen.
Fermi level is the highest energy of occupied states in a solid at zero temperature. The Fermi level in conductors lies in the conduction band, in insulators it lies in the valence band, and in semiconductors it falls in the gap between the conduction band and the valence band. It was named after the Italian physicst Enrico Fermi (1901 - 1954).
Temperature rating is the maximum and minimum temperature at which the material may be used in continuous operation without loss of its basic properties. For example, temperature ratings are often quoted for electrical insulators, specifying the maximum temperature at which they provide adequate protection against electrical breakdown.
Plastic is a material that can be shaped by the application of heat or pressure. Most are based on synthetic polymers although some are the product of natural substances (such as cellulose derivatives, but excluding the rubbers.). They are usually light and permanent solids, being also heat and electric isolators. If the materials soften again when reheated, they are said to be thermoplastic. If, after fashioning, they resist further applications of heat, they are said to be thermoset.
Electrical resistance (R) of a given object is the opposition to the passage of an electric current through that object. The SI unit of electrical resistance is the ohm, represented by the Greek letter omega (Ω). Resistance is the electric potential difference divided by the current when there is no electromotive force in the conductor. This definition applies to direct current. For a conductor of uniform cross section with area A and length L, and whose resistivity is ρ, the resistance is given by
Electrical resistivity, or specific resistance (ρ) is the electric field strength divided by the current density when there is no electromotive force in the conductor. Resistivity is an intrinsic property of a material. Materials with low resistivity are good conductors of electricity and materials with high resistivity are good insulators.
For a conductor of uniform cross section with area A and length L, and whose resistance is R, the resistivity is given by
The SI unit is Ω m.
Generalic, Eni. "Izolator." Croatian-English Chemistry Dictionary & Glossary. 29 June 2022. KTF-Split. {Date of access}. <https://glossary.periodni.com>.
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