Tetrahedral is a molecular shape that results when there are four bonds and no lone pairs around the central atom in the molecule. The atoms bonded to the central atom lie at the corners of a tetrahedron with 109.5° angles between them. Molecules with an tetrahedral electron pair geometries have sp3 hybridization at the central atom. The ammonium ion (NH4+) and methane (CH4) have a tetrahedral molecular geometry.
Trigonal bipyramidal (trigonal bipyramidal shape) is a molecular geometry that results when there are five bonds and no lone pairs on the central atom in the molecule. Three of the bonds are arranged along the atom’s equator, with 120° angles between them; the other two are placed at the atom’s axis. Axial bonds are at right angles to the equatorial bonds. Molecules with an trigonal bipyramidal electron pair geometries have sp3d (or dsp3) hybridization at the central atom. The PCl5 molecule has a trigonal bipyramidal molecular geometry.
Trigonal planar is a molecular shape that results when there are three bonds and no lone pairs around the central atom in the molecule. The pairs are arranged along the central atom’s equator, with 120° angles between them. Molecules with an trigonal planar electron pair geometries have sp2d hybridization at the central atom. The carbonate ion (CO32-) has a trigonal planar geometry.
Trigonal pyramidal is a molecular shape that results when there are three bonds and one lone pair on the central atom in the molecule. Molecules with an tetrahedral electron pair geometries have sp3 hybridization at the central atom. Ammonia (NH3) is a trigonal pyramidal molecule.
Generalic, Eni. "Hibridizacija." Croatian-English Chemistry Dictionary & Glossary. 29 June 2022. KTF-Split. {Date of access}. <https://glossary.periodni.com>.
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