CHEMISTRY GLOSSARY

candela    →   kandela

Candela (cd) is the SI base unit of luminous intensity.

The candela is the luminous intensity, in a given direction, of a source that emits monochromatic radiation of frequency 540×10¹² Hz and that has a radiant intensity in that direction of 1/683 watt per steradian.

carbon    →   ugljik

Carbon has been known since ancient times. The origin of the name comes from the Latin word carbo meaning charcoal. Graphite form of carbon is a black, odourless, slippery solid. Graphite sublimes at 3825 °C. Diamond form is a clear or colored; an extremely hard solid. C60 is Buckminsterfullerine. Carbon black burns readily with oxidants. Carbon is made by burning organic compounds with insufficient oxygen. There are close to ten million known carbon compounds, many thousands of which are vital to organic and life processes. Radiocarbon dating uses the carbon-14 isotope to date old objects.

fluid mechanics    →   mehanika fluida

Fluid mechanics is the study of various properties of the fluid (liquids and gases): velocity, pressure, density and temperature, as functions of space and time.

frequency    →   frekvencija

Frequency (ν) is the number of cycles of a periodic phenomenon divided by time. Hertz (Hz) is the SI derived unit, with a special name, for frequency, equal to s^-1. It was named after the German scientist Heinrich Hertza (1857-1894).

Glauber’s salt    →   Glauberova sol

Glauber’s salt is sodium sulphate decahydrate (Na₂SO₄·10H₂O). Loses water of hydration at 100 °C. Energy storage capacity is more than seven times that of water.

cement    →   cement

Cement is any various substances used for bonding or setting to a hard material. Portland cement is a mixture of calcium silicates and aluminates made by heating limestone (CaCO₃) with clay (containing aluminosilicates) in a kiln. The product is ground to a fine powder. When mixed with water it settles in a few hours and then hardens over a longer period of time due to the formation of hydrated aluminates and silicates.

centrifugation    →   centrifugiranje

Centrifugation is sedimentation of particles under the influence of the centrifugal force and it is used for separation of superfine suspensions. At centrifuging forces up to 10 000 times greater than gravity force are used, and at ultracentrifuge up to 600 000 times as great.

chlorinity    →   klorinitet

Originally chlorinity (symbol Cl) was defined as the weight of chlorine in grams per kilogram of seawater after the bromides and iodides had been replaced by chlorides. To make the definition independent of atomic weights, chlorinity is now defined as 0.3285233 times the weight of silver equivalent to all the halides.

The Mohr-Knudsen titration method served oceanographers for more than 60 years to determine salinity from chlorinity. This modification of the Mohr method uses special volumetric glassware calibrated directly in chlorinity units. The Mohr method uses potassium chromate (K₂CrO₄) as an indicator in the titration of chloride ions chloride (plus a small amount of bromide and iodide) with a silver nitrate (AgNO₃) standard solution.

The other halides present are similarly precipitated.

A problem in the Mohr titration was that silver nitrate is not well suited for a primary standard. The Danish physicist Martin Knudsen (1871-1949) suggested that a standard seawater (Eau de mer Normale or Copenhagen Normal Water) be created and distributed to oceanographic laboratories throughout the world. This water was then used to standardize the silver nitrate solutions. In this way all chlorinity determinations were referred to one and the same standard which gave great internal consistency.

The relationship between chlorinity Cl and salinity S as set forth in Knudsen's tables is

In 1962, however, a better expression for the relationship between total dissolved salts and chlorinity was found to be

hectare    →   hektar

Hectare (ha) is a unit of area equal to 1×10⁴ m². The unit is still used in agriculture.

hecto    →   hekto

Hecto, symbol h, is a prefix used in the metric system to denote 100 times. For example, 100 c = 1 hC.