CHEMISTRY GLOSSARY

concentration    →   koncentracija

1. Group of four quantities characterizing the composition of a mixture with respect to the volume of the mixture (mass, amount, volume and number concentration).

2. Short form for amount (of substance) concentration (substance concentration in clinical chemistry).

Curie temperature    →   Curiejeva temperatura

For a ferromagnetic material, Curie temperature or Curie point (T_C) is the critical temperature above which the material becomes paramagnetic. For iron the Curie point is 760 °C and for nickel 356 °C. It was named after the French physicist Pierre Curie (1859-1906).

density    →   gustoća

In the most common usage, density (ρ) is mass density or mass per unit volume. In Si units it is measured in kg m^-3. More commonly, densities are given in kg dm^-3.

More generally, it is the amount of some quantity (mass, charge, energy, etc.) divided by a length, area, or volume.

Relative density is the ratio of the density of a substance to the density of some reference substance. For liquids or solids, it is the ratio of the density (usually at 20 °C) to the density of water at 4 °C. This quantity was formerly called specific gravity.

enthalpy    →   entalpija

Enthalpy (H) is a thermodynamic property of a system defined by

where U is the internal energy of the system, p its pressure, and V its volume. J.W. Gibbs put the concept of an ensemble forward in 1902. In a chemical reaction carried out in the atmosphere the pressure remains constant and the enthalpy of reaction (ΔH), is equal to

For an exothermic reaction ΔH is taken to be negative.

experiment    →   eksperiment

Experiment is direct observation under controlled conditions. Most experiments involve carefully changing one variable and observing the effect on another variable (for example, changing temperature of a water sample and recording the change volume that results).

face-centered cubic lattice    →   plošno centrirana kubična rešetka

Face-centered cubic lattice (fcc or cubic-F), like all lattices, has lattice points at the eight corners of the unit cell plus additional points at the centers of each face of the unit cell. It has unit cell vectors a =b =c and interaxial angles α=β=γ=90°.

The simplest crystal structures are those in which there is only a single atom at each lattice point. In the fcc structures the spheres fill 74 % of the volume. The number of atoms in a unit cell is four (8×1/8 + 6×1/2 = 4). There are 26 metals that have the fcc lattice.

ferromagnetism    →   feromagnetizam

Ferromagnetism is a type of magnetism in which the magnetic moments of atoms in a solid are aligned within domains which can in turn be aligned with each other by a weak magnetic field. The total magnetic moment of a sample of the substance is the vector sum of the magnetic moments of the component domains. In an unmagnetized piece of ferromagnetic material the magnetic moments of the domains themselves are not aligned; when an external field is applied those domains that are aligned with the field increase in size at the expense of the others. Ferromagnetic materials can retain their magnetisation when the external field is removed, as long as the temperature is below a critical value, the Curie temperature. They are characterised by a large positive magnetic susceptibility.

gas    →   plin

Gas is a state of matter, in which the mollecules move freely and consequently the entire mass tends to expand indefinitely, occupying the total volume of any vessel into which it is introduced. Gases follow, within considerable degree of fidelity, certain laws relating their conditions of pressure, volume and temperature. Gases mix freely with each other, and they can be liquefied through compression or temperature reduction.

graduated pipette    →   graduirana pipeta

Graduated pipettes (Mohr pipette) have a scale divided into units of one and of 1/10th of a millilitre. Because of their wide necks it is less accurate than the volumetric pipette. They are used when taking volume of solutions in which accuracy does not have to be very high. By sucking in (with mouth, propipette or a water pump) the liquid is pulled in a little bit above the mark and the opening of the pipet is closed with a forefingertip. Outer wall of pipet is wiped and, with a slight forefinger loosening, the liquid is released until it reaches the mark 0. A pipette is emptied out by lifting the forefinger off and letting the liquid flow out of the pipette freely.

heat capacity    →   toplinski kapacitet

Heat capacity is defined in general as dQ/dT, where dQ is the amount of heat that must be added to a system to increase its temperature by a small amount dT. The heat capacity at a constant pressure is C_p = (∂H/∂T)_p; that at a constant volume is C_V = (∂E/∂T)_V, where H is enthalpy, E is internal energy, p is pressure, V is volume, and T is temperature. An upper case C normally indicates the molar heat capacity, while a lower case c is used for the specific (per unit mass) heat capacity.