CHEMISTRY GLOSSARY

dialysis    →   dijaliza

Dialysis is a method by which large molecules (such as starch or protein) and small molecules (such as glucose or amino acids) may be separated in a solution by selective diffusion through a semipermeable membrane. Through this kind of membrane dissolved particles pass and colloid dimension particles fall behind. For example, if a mixed solution of starch and glucose is placed in a closed container made of a semipermeable substance (such as cellophane), which is then immersed in a beaker of water, the smaller glucose molecules will pass trough the membrane into the water, while the starch molecules remain behind.

diastereoisomer    →   dijastereoizomer

Diastereoisomers (diastereomers) are stereoisomers of a compound having two or more chiral centers that are not a mirror image of another stereoisomer of the same compound. For example, in the structure below, 1 and 2 are enantiomers and so are 3 and 4; 1 and 3 are diastereoisomers, as are 2 and 4. Unlike enantiomers, diastereoisomers need not have closely similar physical and chemical properties

dioxin    →   dioksin

Dioxin is a general term that describes a group of hundreds of chemicals that are highly persistent in the environment. The most toxic compound is 2,3,7,8-tetrachlorodibenzo-p-dioxin or TCDD. The toxicity of other dioxins and chemicals like PCBs that act like dioxin are measured in relation to TCDD. Dioxin is formed as an unintentional by-product of many industrial processes involving chlorine such as waste incineration, chemical and pesticide manufacturing and pulp and paper bleaching. Dioxin was the primary toxic component of Agent Orange, found at Love Canal in Niagara Falls, NY and was the basis for evacuations at Times Beach, MO and Seveso, Italy.

Dioxin is formed by burning chlorine-based chemical compounds with hydrocarbons. The major source of dioxin in the environment comes from waste-burning incinerators of various sorts and also from backyard burn-barrels. Dioxin pollution is also affiliated with paper mills which use chlorine bleaching in their process, with the production of Polyvinyl Chloride (PVC) plastics, and with the production of certain chlorinated chemicals (like many pesticides).

metal hydride    →   metalni hidrid

Metal hydrides are compounds formed of atoms of a metal combined with atoms of hydrogen in which hydrogen has an oxidation number -1.

mineralization    →   mineralizacija

Mineralization is a process in which organic compounds (e.g. dead plant or animal material) are converted to inorganic compounds (e.g. nitrate, carbon dioxide).

dysprosium    →   disprozij

Dysprosium was discovered by Paul Emile Lecoq de Boisbaudran (France) in 1886. The origin of the name comes from the Greek word dysprositos meaning hard to obtain. It is soft, lustrous, silvery metal. Reacts with oxygen. Reacts rapidly with water; dissolves in acids. Metal ignites and burns readily. Reductant. Dysprosium usually found with erbium, holmium and other rare earths in some minerals such as monazite sand. Dysprosium uses are limited to the experimental and esoteric. Some isotopes of dysprosium are effective absorbers of thermal neutrons and are being considered for use in the control rods in nuclear reactors.

ester    →   ester

Esters are organic compounds formed by a reaction between alcohol and acids. Esters formed from carboxylic acids have the general formula RCOOR’. Triesters, molecules containing three ester groups, occur in nature as oils and fats.

ether    →   eter

Ethers are organic compounds with a formula R-O-R, where R is not equal to H. They may be derived from alcohols by elimination of water, but the major method is catalytic hydration of olefins. They are volatile highly flammable compounds; when containing peroxides they can detonate on heating. The term ether is often used synonymously with diethyl ether.

explosive    →   eksploziv

Explosive is a compound or mixture that, when ignited or detonated, undergoes rapid violent chemical reaction that produces large amount of gas and heat, accompanied by light, sound and a high pressure shock wave.

mixture    →   smjesa

Mixture is a heterogeneous association of substances where various individual substances retain their identities and can usually be separated by mechanical means. Includes solutions or compounds but does not include alloys or amalgams.