Calomel electrode is a type of half cell in which the electrode is mercury coated with calomel (Hg2Cl2) and the electrolyte is a solution of potassium chloride and saturated calomel. In the calomel half cell the overall reaction is
Table: Dependence of potential of calomel electrode upon temperature and concentration of KCl according to standard hydrogen electrode
Potential vs. SHE / V | |||
---|---|---|---|
t / °C | 0.1 mol dm-3 | 3.5 mol dm-3 | sat. solution |
15 | 0.3362 | 0.254 | 0.2511 |
20 | 0.3359 | 0.252 | 0.2479 |
25 | 0.3356 | 0.250 | 0.2444 |
30 | 0.3351 | 0.248 | 0.2411 |
35 | 0.3344 | 0.246 | 0.2376 |
Calorimeter is an instrument used to measure the energy absorbed or released in a chemical reaction. It also used in determining specific heat.
Chemical engineering is the branch of engineering that is concerned with the design, construction and operation of the plants and machinery used in industrial chemical processes.
Chemical kinetics is an area of chemistry that studies rates and mechanisms of chemical reactions.
Chemical property is a property observed when a substance undergoes a transformation into one or more new substances. Measurement of a chemical property involves a chemical change. For example, determining the flammability of petrol involves burning it, producing carbon dioxide and water.
Chemical reaction is a change of chemical properties of substances which react with each other. By means of a chemical reaction new substances are created by bond breaking between atoms and molecules of reactants and their reuniting in a new way, thereby creating products. Chemical reactions can be shown by chemical equations.
Carat (ct.) is a metric unit of mass for the weighing of precious metals, precious stone and gems (e.g. diamond, ruby, sapphire).
Carat (ct, Kt) corresponds to the mass fraction of gold in precious alloys used in jewellery.
1 ct = 0.4167 %
24 ct = 100 %
24 carat gold is pure gold, 18 carat is 75 % gold and 25 % of some other metal such as silver or copper.
Carbohydrates (often called carbs for short) are polyhydroxy aldehydes or ketones, or substances that yield such compounds on hydrolysis. They are also known as saccharides, a term derived from the Latin word saccharum for sugar. Carbohydrates are the most abundant class of compounds in the biological world, making up more than 50 % of the dry weight of the Earth’s biomass. Every type of food we eat can have its energy traced back to a plant. Plants use carbon dioxide and water to make glucose, a simple sugar, in photosynthesis. Other carbohydrates such as cellulose and starch are made from the glucose. Light from the sun is absorbed by chlorophyll and this is converted to the energy necessary to biosynthesize carbohydrates
The term carbohydrate was applied originally to monosaccharides, in recognition of the fact that their empirical composition can be expressed as Cx(H2O)y. Later structural studies revealed that these compounds were not hydrates but the term carbohydrate persists.
Carbohydrates are generally classed as either simple or complex. Simple sugars, or monosaccharides, are carbohydrates that can’t be converted into smaller subunits by hydrolysis. Complex carbohydrates are made of two (disaccharides) or more (oligosaccharides, polysaccharides) simple sugars linked together by acetal (glycosidic) bonds and can be split into the former by hydrolysis.
Carbon has been known since ancient times. The origin of the name comes from the Latin word carbo meaning charcoal. Graphite form of carbon is a black, odourless, slippery solid. Graphite sublimes at 3825 °C. Diamond form is a clear or colored; an extremely hard solid. C60 is Buckminsterfullerine. Carbon black burns readily with oxidants. Carbon is made by burning organic compounds with insufficient oxygen. There are close to ten million known carbon compounds, many thousands of which are vital to organic and life processes. Radiocarbon dating uses the carbon-14 isotope to date old objects.
Generalic, Eni. "OFICINAVIRTUAL.ISSSTE.GOB.MX." Croatian-English Chemistry Dictionary & Glossary. 29 June 2022. KTF-Split. {Date of access}. <https://glossary.periodni.com>.
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