CHEMISTRY GLOSSARY

Bohr magneton    →   Bohrov magneton

Bohr magneton (μ_B) is the atomic unit of magnetic moment, defined as

where h is Planck’s constant, m_e the electron mass, and e the elementary charge. It is the moment associated with a single electron spin.

bomb calorimeter    →   kalorimetrijska bomba

Bomb calorimeter is a type of constant-volume calorimeter used in measuring the heat of combustion of samples which can be burned in oxygen. Four essential parts are required in any bomb calorimeter:

1. a bomb or vessel in which the combustible charges can be burned,
2. a bucket or container for holding the bomb in a measured quantity of water, together with a stirring mechanism,
3. an insulating jacket to protect the bucket from transient thermal stresses during the combustion process, and
4. a thermometer or other sensor for measuring temperature changes within the bucket.

covalentity    →   kovalentnost

Covalentity is a maximum number of covalent bond that one atom can make, it is equal to the number of hydrogen atoms that are combined with other atoms. It is usually constant.

Boyle’s law    →   Boyleov zakon

Boyle’s law (sometimes referred to as the Boyle-Mariott’s law) is the empirical law, exact only for an ideal gas, which states that the volume of a gas is inversely proportional to its pressure at constant temperature.

Bunsen burner    →   Bunsenov plamenik

Bunsen burner is a standard source of heat in the laboratory. German chemist Roberts Bunsen (1811-1899) improved the burner's design, which had been invented by Faraday, to aid his endeavors in spectroscopy. The Bunsen burner has a vertical metal tube through which a fine jet of fuel gas is directed. Air is drawn in through airholes near the base of the tube and the mixture is ignited and burns at the tube’s upper opening. The flow of this air is controlled by an adjustable collar on the side of the metal tube. When the whole is closed a yellow safety flame is displayed. Where as when the whole is open it displays a power dull blue flame with a faint blue outer flame with a vibrant blue core used u for combustion and hearting. The flame can reach temperatures of 1 500 °C.

Bunsen, Robert Wilhem    →   Bunsen, Robert Wilhem

Robert Wilhem Bunsen (1811-1899) is a German chemist who held professorships at Kassel, Marburg and Heidelberg. His early researches on organometallic compound of arsenic cost him an eye in an explosion. Bunsen's most important work was in developing several techniques used in separating, identifying, and measuring various chemical substances. He also improvement chemical battery for use in isolating quantities of pure metals - Bunsen battery.

The essential piece of laboratory equipment that has immortalized the name of Bunsen was not invented by him. Bunsen improved the burner's design, which had been invented by Faraday, to aid his endeavors in spectroscopy. Use of the Bunsen burner in conjunction with a glass prism led to the development of the spectroscope in collaboration with the German physicist Gustav Kirchoff and to the spectroscopic discovery of the elements rubidium (1860) and cesium (1861).

equation of state    →   jednadžba stanja

Equation of state is an equation relating the pressure, volume, and temperature of a substance or system. Equation of state for ideal gas

where p is pressure, V molar volume, T temperature, and R the molar gas constant (8.314 JK^-1mol^-1).

Charles’ law    →   Charlesov zakon

The volume of a fixed mass of gas at a constant pressure expand by the constant fraction of its volume at 0 °C. For each Celsius or kelvin degree its temperature is raised. For any ideal gas fraction it is approximately 1/273. This can be expressed by the equation

were V° is the volume at 0°C and V is its volume at t°C.

This is equivalent to the statement that the volume of a fixed mass of gas at a constant pressure is proportional to its thermodynamic temperature

This law also know as Gay-Lussac’s law.

An equation similar to the one given above applies to pressures for ideal gases:

chemical potential    →   kemijski potencijal

For a mixture of substances, the chemical potential of constituent B (μ_B) is defined as the partial derivative of the Gibbs energy G with respect to the amount (number of moles) of B, with temperature, pressure, and amounts of all other constituents held constant.

Also called partial molar Gibbs energy. Components are in equilibrium if their chemical potentials are equal.

composition of ocean water    →   sastav oceanske vode

The proportions of the major constituents of ocean water are almost constant throughout the world. Salinity (total salt content) and the concentrations of individual chemical constituents in sea wateris given the units psu (practical salinity units). For most purposes one can assume that the new unit, psu, and the older unit, ‰, are synonymous.

The average composition of the ocean water is as shown on the following table.