CHEMISTRY GLOSSARY

solvation    →   solvatacija

Solvation is the process by which solvent molecules surround and interact with solute ions or molecules.

spontaneously combustible    →   samozapaljivi materijal

Spontaneously combustible materials are materials that can ignite without an external source of heat. Heat sufficient to reach the ignition temperature may be generated by reaction with oxygen in the air, by the absorption of moisture, from heat generated during processing, or even from radioactive decay.

standardisation    →   standardizacija

Standardisation is a process of determining the exact concentration of secondary standard solution.

stereospecific reaction    →   stereospecifična reakcija

Stereospecific reactions are reactions that proceed predominantly to a single stereoisomeric product out. All metabolic conversions involving chiral molecules are stereospecific.

electrodeposition    →   elektrodepozicija

Electrodeposition is a process of depositing solid materials on an electrode surface using electrolysis. It is a somewhat loosely used term that is applied to many technologies. There are a number of metal deposition technologies. However, not only metals but also different compounds can be electrodeposited. This is used most often for the formation of oxides (such as manganese dioxide and lead dioxide) by anodic oxidation of dissolved salts.

electrodialysis    →   elektrodijaliza

Electrodialysis is a procedure of dialysis accelerated with an electric field. Dialyser is divided into three sections. Solution flows through the middle section, between two semipermeable membranes alternately to positive ions and negative ions. An electrodes are placed in the neighbouring sections. Under the influence of electric field, positive ions will travel towards the cathode (the negative electrode), and negative ions towards the anode (the positive electrode), whereby travelling of ions through the membrane is accelerated. In this way, the feed water is separated into two streams: one of pure water and the other of more concentrated solution.

electrolytic cell    →   elektrolitska ćelija

Electrolytic cell is an electrochemical cell that converts electrical energy into chemical energy. The chemical reactions do not occur spontaneously at the electrodes when they are connected through an external circuit. The reaction must be forced by applying an external electric current. It is used to store electrical energy in chemical form (rechargeable battery). It is also used to decompose or produce (synthesise) new chemicals by the application of electrical power. This process is called electrolysis, e.g., water can be decomposed into hydrogen gas and oxygen gas. The free energy change of the overall cell reaction is positive.

entropy    →   entropija

Entropy (S) is a measure of the unavailability of a system’s energy to do work; in a closed system, an increase in entropy is accompanied by a decrease in energy availability. When a system undergoes a reversible change the entropy (S) changes by an amount equal to the energy (Q) transferred to the system by heat divided by the thermodynamic temperature (T) at which this occurs.

All real processes are to a certain extent irreversible changes and in any closed system an irreversible change is always accompanied by an increase in entropy.

thermit welding    →   termitno zavarivanje

Thermit welding is a group of welding processes in which fusion is produced by heating with superheated liquid metal resulting from a chemical reaction between a metal oxide and aluminium.

toxic chemical    →   bojni otrov

Toxic chemical means any chemical which through its chemical action on life processes can cause death, temporary incapacitation, or permanent harm to humans or animals. This includes all such chemicals, regardless of their origin or of their method of production, and regardless of whether they are produced in facilities, in munitions or elsewhere.