CHEMISTRY GLOSSARY
mendelevium → mendelevij
Mendelevium was discovered by Albert Ghiorso, Bernard G. Harvey, Gregory R. Choppin, Stanley G. Thompson and Glenn T. Seaborg (USA) in 1955. Named in honour of Dimitri Mendeljejev, the Russian chemist who devised the periodic table. It is synthetic radioactive metal. Mendelevium was made by bombarding einsteinium with helium ions.
electrode of the first kind → elektroda prvog reda
Electrode of the first kind is a simple metal electrode immersed in a solution containing its own ion (e.g., silver immersed in a silver nitrate solution). The equilibrium potential of this electrode is a function of the concentration (more correctly of activity) of the cation of the electrode metal in the solution (see Nernst’s electrode potential equation).
electrode potential → elektrodni potencijal
Electrode potential is defined as the potential of a cell consisting of the electrode in question acting as a cathode and the standard hydrogen electrode acting as an anode. Reduction always takes place at the cathode, and oxidation at the anode. According to the IUPAC convention, the term electrode potential is reserved exclusively to describe half-reactions written as reductions. The sign of the half-cell in question determines the sign of an electrode potential when it is coupled to a standard hydrogen electrode.
Electrode potential is defined by measuring the potential relative to a standard hydrogen half cell
The convention is to designate the cell so that the oxidised form is written first. For example
The e.m.f. of this cell is
By convention, at p(H2) = 101325 Pa and a(H+) = 1.00, the potential of the standard hydrogen electrode is 0.000 V at all temperatures. As a consequence of this definition, any potential developed in a galvanic cell consisting of a standard hydrogen electrode and some other electrode is attributed entirely to the other electrode
electron configuration → elektronska konfiguracija
The electron configuration shows how many electrons there are in an atom or ion and their distribution along orbitals (see Table of electronic configuration of elements). Structure and all regularity in the periodic system depend upon electronic configuration of atoms of elements. Characteristics of elements mainly depend on electronic configuration of the outer shell. Refilling of the new electronic shell atoms of elements of similar electronic configuration emerge as well as in the previous shell, which adds up to periodicities of characteristics of elements.
Citing this page:
Generalic, Eni. "/tab." Croatian-English Chemistry Dictionary & Glossary. 29 June 2022. KTF-Split. {Date of access}. <https://glossary.periodni.com>.
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