CHEMISTRY GLOSSARY

referent electrode    →   referentna elektroda

Referent electrode is an electrode whose potential is known and completely independent of analyte concentration. Mostly used referent electrodes are calomel and silver/silver chloride electrode.

Table: Dependence of referent electrodes potentials on KCl concentration

refractometer    →   refraktometar

Refractometer is an optical device used from measurement of refractive index. A refractometer takes advantage of the fact that light bends as it passes through different materials. It can be used to measure the salinity of water or the amount of sugar in fresh grapes. Refractometers are available with or without automatic temperature compensation (ATC).

When using a conventional saltwater refractometer, a sample is placed on an optical prism in the sample window. As light shines through the sample, it is bent according to the salinity of the water, and casts a shadow on the scale that is visible through the eyepiece. Salinity is read directly through the eyepiece.

rhenium    →   renij

Rhenium was discovered by Walter Noddack, Ida Tacke and Otto Berg (Germany) in 1925. The origin of the name comes from the Latin word Rhenus meaning river Rhine. It is rare and costly, dense, silvery-white metal. Tarnishes in moist air. Resists corrosion and oxidation. Dissolves in nitric and sulfuric acids. Has a very high melting point. Rhenium is found in small amounts in gadolinite and molybdenite. Mixed with tungsten or platinum to make filaments for mass spectrographs. Its main value is as a trace alloying agent for hardening metal components that are subjected to continuous frictional forces.

salinity    →   salinitet

Salinity (S) is a measure of the quantity of dissolved salts in seawater. It is formally defined as the total amount of dissolved solids in seawater in parts per thousand (‰) by weight when all the carbonate has been converted to oxide, the bromide and iodide to chloride, and all organic matter is completely oxidized.

Chlorinity is the oldest of the salinity measures considered and is still a corner-stone in the study of dissolved material in seawater. Based on the principle of constant relative proportions it provides a measure of the total amount of dissolved material in seawater in terms of the concentration of halides. The relationship between chlorinity (Cl) and salinity as set forth in Knudsen’s tables is

In 1962, however, a better expression for the relationship between total dissolved salts and chlorinity was found to be

Practical Salinity (S_P) was introduced as a replacement for Chlorinity. Practical Salinity is is relatively easy to measure using standard conductometers, measurements are more precise and less time consuming than measurements of Chlorinity and accurate measurements can even be made in situ. Practical salinity S_P is defined on the Practical Salinity Scale of 1978 (PSS-78) in terms of the conductivity ratio K₁₅ which is the electrical conductivity of the sample at temperature t₆₈ = 15 °C and pressure equal to one standard atmosphere, divided by the conductivity of a standard potassium chloride (KCl) solution at the same temperature and pressure. The mass fraction of KCl in the standard solution is 0.0324356 (32.4356 g of KCl in 1 kg of solution).

Note that Practical Salinity is a unit-less quantity. Though sometimes convenient, it is technically incorrect to quote Practical Salinity in "psu". For most purposes one can assume that the psu and the ‰, are synonymous.

The global average salinity of ocean waters is about 35 ‰, that is, about 35 g of solid substances are dissolved in 1 kg of seawater.

salt water    →   slana voda

Salt water is the water of the sea and the ocean. This water contains a relatively high percentage of dissolved salt (about 35 g of salt per 1 000 g of sea water.). About 90 % of that salt would be sodium chloride, or ordinary table salt.

The salinity of ocean water varies. It is affected by such factors as melting of ice, inflow of river water, evaporation, rain, etc.

saturated fatty acid    →   zasićena masna kiselina

Saturated fatty acid is a fatty acid carrying the maximum possible number of hydrogen atoms (It doesn’t have any double bounds in the alkyl chain). The most important of these are:

scandium    →   skandij

Scandium was discovered by Lars Fredrik Nilson (Sweden) in 1879. The origin of the name comes from the Latin word Scandia meaning Scandinavia. It is fairly soft, silvery-white metal. Burns easily. Tarnishes readily in air. Reaction with water releases hydrogen. Reacts with air and halogens. Scandium occurs mainly in the minerals thortveitile (~34 % scandium) and wiikite. Also in some tin and tungsten ores. Pure scandium is obtained as a by-product of uranium refining. Scandium metal is used in some aerospace applications. Scandium oxide (Sc₂O₂) is used in the manufacture of high-intensity electric lamps. Scandium iodide (ScI₃) is used in lamps that produce light having a colour closely matching natural sunlight.

Schrodinger equation    →   Schrodingerova jednadžba

Schrödinger equation is the basic equation of wave mechanics which, for systems not dependent on time, takes the form:

where Ψ is the wavefunction, V is the potential energy expressed as a function of the spatial coordinates, E its total energy, ² is the Laplacian operator, h is Planck’s constant, and m is the mass.

second    →   sekunda

Second (s) is the SI base unit of time.

The second is the duration of 9 192 631 770 periods of the radiation corresponding to the transition between the two hyperfine levels (F = 4, m_F = 0 to F = 3, m_F = 0) of the ground state of the caesium 133 atom.

sedimentation    →   sedimentiranje

Sedimentation is a process of separating specifically heavier, suspended matter, than the solution is. Solid matter settles on the bottom of the vessel and the liquid above it is poured off. The settling zone is the largest portion of the sedimentation basin. This zone provides the calm area necessary for the suspended particles to settle. The sludge zone, located at the bottom of the tank, provides a storage area for the sludge before it is removed for additional treatment or disposal.