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Electronegativity is a parameter originally introduced by L. Pauling which describes, on a relative basis, the power of an atom to attract electrons. For example, in hydrogen chloride, the chlorine atom is more electronegative than the hydrogen and the molecule is polar, with a negative charge on the chlorine atom.
There are various ways of assigning values for the electronegativity of an element. Pauling electronegativities are based on bond dissociation energies using a scale in which fluorine, the most electronegative element, has the value 4 and francium, the lowest electronegative element, has the value 0.7.
Atoms can give one or more electrons for bond forming. The valence of any atom, which comes from stechiometrical relation of interbonded atoms, is called an oxidation number or an oxidation degree. Oxidation number of atoms in elementary state is zero. An atom of greater electronegativity has a negative, and an atom of lesser electronegativity has a positive oxidation number.
Pauling scale is a numerical scale of electronegativities based on bond-energy calculations for different elements joined by covalent bonds. Electronegativity is the power of an atom when in a molecule to attract eletrons to itself. Fluorine is the most electronegative element with a Pauling electronegativity value of 4.
Generalic, Eni. "Elektronegativnost." Croatian-English Chemistry Dictionary & Glossary. 29 June 2022. KTF-Split. {Date of access}. <https://glossary.periodni.com>.
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