CHEMISTRY GLOSSARY

Markovnikov’s rule    →   Markovnikovljevo pravilo

Markovnikov’s rule: when an asymmetrical alkene reacts with a hydrogen halide to give an alkyl halide, the hydrogen adds to the carbon of the alkene that has the greater number of hydrogen substituents, and the halogen to the carbon of the alkene with the fewer number of hydrogen substituents.

metal hydride    →   metalni hidrid

Metal hydrides are compounds formed of atoms of a metal combined with atoms of hydrogen in which hydrogen has an oxidation number -1.

molar quantity    →   molarna veličina

Molar quantity is often convenient to express an extensive quantity (e.g., volume, enthalpy, heat capacity, etc.) as the actual value divided by the amount of substance (number of moles). The resulting quantity is called molar volume, molar enthalpy, etc.

molecular formula    →   molekularna formula

Molecular formula is a formula which represents one molecule of an element or a compound, and the number of atoms in each one of them.

monomer    →   monomer

Monomer is a simple molecule which is capable of combining with a number of like or unlike molecules to form a polymer. Monomer is repeating structure unit within a polymer.

neutral substance    →   neutralna tvar

Neutral substance is a substance that shows no acid or base properties, has an equal number of hydrogen and hydroxyl ions and does not change the colour of litmus-paper.

face-centered cubic lattice    →   plošno centrirana kubična rešetka

Face-centered cubic lattice (fcc or cubic-F), like all lattices, has lattice points at the eight corners of the unit cell plus additional points at the centers of each face of the unit cell. It has unit cell vectors a =b =c and interaxial angles α=β=γ=90°.

The simplest crystal structures are those in which there is only a single atom at each lattice point. In the fcc structures the spheres fill 74 % of the volume. The number of atoms in a unit cell is four (8×1/8 + 6×1/2 = 4). There are 26 metals that have the fcc lattice.

Faraday’s laws of electrolysis    →   Faradayevi zakoni elektrolize

Faraday’s laws of electrolysis are two laws found by British chemist and physicist Michael Faraday (1791-1867) in his experiments on electrolysis:

1. The quantity of matter extracted on the electrode is proportional to the quantity of charge (Q = I·t) which has flown in electrolysis time.

where z = number of electrons changed in reaction and F = Faraday’s constant which equals 96 487 C mol^-1.

2. The masses of the elements liberated by the same quantity of electricity are directly proportional to their chemical equivalents.

96 487 C will discharge 1 mol Ag and 1/2 mol Cu. The relevant half reactions are:

nitride    →   nitrid

Nitrides are compounds of nitrogen with metal in which nitrogen has an oxidation number -3, are hard and resistant to high temperatures.

nuclide    →   nuklid

Nuclide is a species of atoms in which each atom has identical atomic number Z and identical mass number A. For example, a carbon-14 (C-14 or ¹⁴C) nuclide is the nucleus of a carbon atom, which has six protons and eight neutrons.