CHEMISTRY GLOSSARY

PE    →   PE

PE is an abbreviation for polyethylene, usually abbreviated as HDPE (High Density Polyethylene), MDPE (Medium Density Polyethylene), and LDPE (Low Density Polyethylene).

ion selective electrode    →   ion selektivne elektrode

Ion selective electrode (ISE) is an electrode or electrode assembly with a potential that is dependent on the concentration of an ionic species in the test solution and is used for electroanalysis. Ion-selective electrodes are often membrane type electrodes.

ionic bond    →   ionska veza

Ionic bond is a strong force of attraction holding atoms together in a molecule or crystal. Typically chemical bonds have energies of about 100 kJ mol^-1. Ionic bond is a bond at which one of the participants, during the procedure of bonding, gives away its unpaired electrons to another atom so that both can achieve electron arrangement of the closest noble gas. In order to form an ionic bond one of the atoms must cross to the positively charged ion by losing certain number of electrons and the other atom must receive those electrons and cross to the negatively charged ion.

ionic radius    →   ionski radijus

Ionic radius is the radius of anions and cations in crystalline ionic compounds, as determined by consistently partitioning the center-to-center distance of ions in those compounds. In general, negative ions have larger ionic radii than positive ions.

ionisation    →   ionizacija

Ionisation is the process of producing ions. Certain molecules ionise in a solution; for example, acids ionise when dissolved in water.

Electron transfer also causes ionisation in certain reactions, for example sodium and chlorine react by transfer of a valence electron from the sodium atom to the chlorine atom to form the ions that constitute a sodium chloride crystal.

iridium    →   iridij

Iridium was discovered by Smithson Tennant (England) in 1803. The origin of the name comes from the Latin word iris, meaning rainbow, because its salts are highly colored. It is heavy, brittle, white metal. Unreactive in air, water and acids. Attacked by fused NaOH. Metal ignites and burns readily. Iridium is found in gravel deposits with platinum. Used with osmium to tip gold pen points, to make crucible and special containers. Also to make alloys used for standard weights and measures and heat-resistant alloys. Also as hardening agent for platinum.

iron    →   željezo

Iron has been known since ancient times. The origin of the name comes from the Latin word ferrum meaning iron. It is malleable, ductile, silvery-white metal. Exposed surfaces form red-brown oxides. Forms very strong alloys (steel). Ferromagnetic. Metal dust flammable. Fourth most abundant element in the earth’s crust. Iron is obtained from iron ores. Pure metal produced in blast furnaces by layering limestone, coke and iron ore and forcing hot gasses into the bottom. This heats the coke red hot and the iron is reduced from its oxides and liquefied where it flows to the bottom. Iron is the most common metal in human society. More than 90 % of all metal refined in the world is iron. Used in steel and other alloys. It is the chief constituent of hemoglobin which carries oxygen in blood vessels. Its oxides are used in magnetic tapes and disks.

isoleucine    →   izoleucin

Isoleucine is hydrophobic amino acids with aliphatic side chain. It is one of the three amino acids having branched hydrocarbon side chains. The side chains of these amino acids are not reactive but, these residues are critically important for ligand binding to proteins, and play central roles in protein stability. Isoleucine is an essential amino acid, which means that humans cannot synthesize it, so it must be ingested.

• Abbreviations: Ile, I
• IUPAC name: 2-amino-3-methylpentanoic acid
• Molecular formula: C₆H₁₃NO₂
• Molecular weight: 131.12 g/mol

Joule-Thomson coefficient    →   Joule-Thompsonov koeficijent

Joule-Thomson coefficient (μ) is a parameter which describes the temperature change when a gas expands adiabatically through a nozzle from a high pressure to a low pressure region. It is defined by

where H is enthalpy.

Joule-Thomson’s effect    →   Joule-Thomsonov efekt

Temperature of ideal gas will not be changed when it is repressed to a lower pressure, but when real gases are repressed to a lower pressure, a lower or higher temperature change appears under high pressures. The temperature change which appears at real gas expansion in a system into which energy is not brought is called Joule-Thomson’s effect. It was determined that when air is repressed by 1 bar, its temperature drops by 0.25 °C. That minute effect is completely irrelevant for most technical processes, but is also used in gas liquefying procedure.