CHEMISTRY GLOSSARY

osmometry    →   osmometrija

Osmometry is a determination of the average molecular weight of a dissolved substance from measurements of osmotic pressure.

osmosis    →   osmoza

Osmosis is the flow of a solvent in a system in which two solutions of different concentration are separated by a semipermeable membrane which cannot pass solute molecules. The solvent will flow from the side of lower concentration to that of higher concentration, thus tending to equalise the concentrations. The pressure that must be applied to the more concentrated side to stop the flow is called the osmotic pressure.

hybridization    →   hibridizacija

Hybridization is an internal linear combination of atomic orbitals, in which the wave functions of the atomic orbitals are added together to generate new hybrid wave functions. The new orbitals which are formed are hybrids of the originals and have properties (shape, size and energy) that are somewhere in between.

hydration    →   hidratacija

Hydration is addition of water or the elements of water (i.e. H and OH) to a molecular entity. The term is also used in a more restricted sense for the process:

hydrogen    →   vodik

Hydrogen was discovered by Sir Henry Cavendish (England) in 1766. The origin of the name comes from the Greek words hydro and genes meaning water and generate. It is colourless, odourless gas, burns and forms explosive mixtures in air. Reacts violently with oxidants. Hydrogen is the most abundant element in the universe. Commercial quantities of hydrogen are produced by reacting superheated steam with methane or carbon. In lab work from reaction of metals with acid solutions or electrolysis. Most hydrogen is used in the production of ammonia and in metal refining. Also used as fuel in rockets. Its two heavier isotopes (deuterium and tritium) used respectively for nuclear fusion.

hydrogen bond    →   vodikova veza

Hydrogen is a bond formed by a hydrogen atom to an electronegative atom, and is denoted by dashed lines H-X---H-B. A hydrogen atom covalently bound to an oxygen (electronegative atom) has a significant positive charge and can form a weak bond to another electronegative atom.

overpotential    →   prenapon

Overpotential (η) is a potential that must be applied in an electrolytic cell in addition to the theoretical potential required to liberate a given substance at an electrode. The value depends on the electrode material and on the current density.

oxalate    →   oksalat

Oxalates are salts of oxalic acid (H₂C₂O₄), an acid found in many plants and vegetables.

oxidation    →   oksidacija

The term oxidation originally meant a reaction in which oxygen combines chemically with another substance. More generally, oxidation is a part of a chemical reaction in which a reactant loses electrons (increases oxidation number). Simultaneous reduction of a different reactant must occur (redox reaction).

hydrolysis    →   hidroliza

Hydrolysis is a chemical reaction in which water reacts with another substance to form two or more new substances. This involves ionisation of the water molecule, as well as splitting of the compound hydrolysed, e.g.

Examples are conversion of starch to glucose by water in the presence of suitable catalysts and a reaction of the ions of a dissolved salt to form various products, such as acids, complex ions, etc.