Cross-linking is an attachment of two chains of polymer molecules by bridges, composed of either an element, a group, or a compound, that join certain carbon atoms of the chains by primary chemical bonds, as indicated in the schematic diagram
Cross-linking occurs in nature in substances made up of polypeptide chains that are joined by the disulfide bonds of the cysteine residue, as in keratins or insulin. Cross-linking can be artificially effected, either adding a chemical substance (cross-linking agent), or by subjecting the polymer to high-energy radiation. Examples are: vulcanisation of rubber with sulphur, cross-linking of polystyrene with divinylbenzene, or cross-linking of polyethylene by means of high-energy radiation.
Cross-linking has the effect of changing a plastic from thermoplastic to thermosetting. Thus, it also increases strength, heat and electrical resistance, and especially resistance to solvents and other chemicals.
Fermi level is the highest energy of occupied states in a solid at zero temperature. The Fermi level in conductors lies in the conduction band, in insulators it lies in the valence band, and in semiconductors it falls in the gap between the conduction band and the valence band. It was named after the Italian physicst Enrico Fermi (1901 - 1954).
Crucible is used for heating small amounts of solid in an oven to very high temperatures. Crucibles are usually made out of porcelain, platinum, nickel or iron.
Crude oil (petroleum) is a fossil fuel formed from plant and animal remains many million of years ago. It is occasionally found in springs or pools but is usually drilled from wells beneath the earth’s surface. Crude oil is a mixture of hydrocarbons with small quantities of other chemicals such as sulphur, nitrogen and oxygen. Crude is the raw material which is refined into petrol, heating oil, jet fuel, propane, petrochemicals, and other products.
Cryogenic fluids are used for accessing low temperatures, usually below -150 °C. Cryogenic temperatures are achieved by the rapid evaporation of volatile liquids. The most common laboratory cryogenic fluids are liquid nitrogen (-196 °C). Nitrogen gas is colorless and odorless. The cloud formed when pouring liquid nitrogen is condensed water vapour from the air, not nitrogen gas.
Cryogenic fractionation is a process of separation of gases by cooling them until they enter their liquid state. Large scale gas production companies use this method to produce liquid oxygen, liquid nitrogen etc. Gases have different boiling points (the temperature at which they change from liquid to gas). Oxygen has a boiling point of -183 °C, and nitrogen a boiling point of -195.8 °C. Therefore by cooling the gas mixture to -183 °C, the oxygen can be collected as liquid and the nitrogen remains its gaseous form.
Generalic, Eni. "S.t.p.." Croatian-English Chemistry Dictionary & Glossary. 29 June 2022. KTF-Split. {Date of access}. <https://glossary.periodni.com>.
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