CHEMISTRY GLOSSARY

aliquot    →   alikvot

Aliquot is a known volume of liquid that represents a part of some larger volume. It is usually taken with a pipette from a measured flask.

alkaloid    →   alkaloid

Alkaloids are basic nitrogen organic compounds (mostly heterocyclic) derived from plants and having diverse pharmacological properties. Alkaloids include morphine, cocaine, atropine, quinine, and caffeine, most of which are used in medicine as analgesics or anaesthetics. Some alkaloids are poisonous, e.g. strychnine and coniine, and colchicine inhibit cell division.

active site    →   aktivno mjesto

Active site is a pocket or crevice on an enzyme molecule that fits reactant molecules like a hand in a glove. The active site lowers the activation energy for reaction

activity    →   aktivitet

Activity (a) is a thermodynamic function used in place of concentration in equilibrium constants for reactions involving nonideal gases and solutions. For the species i activity is defined as

where a_i is the activity of the species i, c_i is its molar concentration, and f_i is a dimensionless quantity called the activity coefficient.

acylaction reaction    →   reakcije aciliranja

Acylaction reaction involves the introduction of an acyl group (RCO-) into a compound. An alkyl halide is reacted with an alcohol or a carboxylic acid anhydride e.g.

The introduction of an acetyl group (CH₃CO-) is acetylation, a process used for protecting -OH groups in organic synthesis.

addition reactions    →   reakcije adicije

Addition reactions are normally occur with unsaturated compounds and involve the addition of one molecule (called the reactant) across the unsaturated bond (i.e. the double bond or the triple bond) of another molecule (called the substrate) to give a single product, formed by the combination of both reacting molecules.

For example, bromine adds across the double bond of ethene in an addition reaction to form dibromoethane.

adenosine triphosphate    →   adenozin trifosfat

Adenosine triphosphate (ATP) is nucleotide that is of fundamental importance as a carrier of chemical energy in all living organisms. It consists of adenin linked to D-ribose).

allomorphism    →   alomorfija

Allomorphism is the existence of chemical substances with same chemical composition in two or more crystalline forms. See Polymorphism.

alloy    →   legura

Alloys are solid solutions of metal or nonmetal in metal and are prepared in order to obtain certain properties. In this way alloys can have greater hardness, corrosion resistance or some other properties gained from the metal they are composed.

alpha rays    →   alfa-zrake

Alpha rays are a stream of alpha particles. Alpha rays rapidly dissipate their energy as they pass through materials. They were discovered by the British physicist Ernest Rutherford (1871-1937), a New Zealander by birth, in 1903.