Silver coulometer consists of a platinum vessel which acts as a cathode and contains a solution of pure silver nitrate as an electrolyte (c(AgNO3) = 1 mol/L). A rod of pure silver enclosed in a porous pot acts as the anode. The current density at the anode should not exceed 0.2 Acm-2. After electrolysis, the electrolyte is taken out and the platinum vessel is washed, dried and weighed. The increase in the weight gives the amount of silver deposited (96500 C of electricity deposits 107.88 g of silver). From the mass of the silver deposited, the coulomb involved in the reaction can be calculated.
Silver/silver-chloride electrode is by far the most common reference type used today because it is simple, inexpensive, very stable and non-toxic. It is mainly used with saturated potassium chloride electrolyte, but can be used with lower concentrations such as 3.5 mol dm-3 or 1 mol dm-3 potassium chloride. Silver/silver-chloride electrode is a referent electrode based on the following halfreaction
| Potential vs. SHE / V | ||
|---|---|---|
| t / °C | 3.5 mol dm-3 | sat. solution |
| 15 | 0.212 | 0.209 |
| 20 | 0.208 | 0.204 |
| 25 | 0.205 | 0.199 |
| 30 | 0.201 | 0.194 |
| 35 | 0.197 | 0.189 |
Simple or primitive cubic lattice (sc or cubic-P) has one lattice point at the each corner of the unit cell. It has unit cell vectors a = b = c and interaxial angels α=β=γ=90°.
The simplest crystal structures are those in which there is only a single atom at each lattice point. In the sc structures the spheres fill 52 % of the volume. The number of atoms in a unit cell is one (8×1/8 = 1). This is only one metal (α-polonium) that have the sc lattice.
Simple magnifier is a converging lens, placed between the object and the eye, with the object inside the focal length of the lens. The angular magnification of a simple magnifier is:
where f is the focal length of the lens and 15 cm is the near point distance for a normal eye. The image of the object is virtual, which means that the rays do not actually pass through the point of intersection, that is, it can not be seen on a screen.
Simple or primitive monoclinic lattice (monoclinic-P) has one lattice point at the each corner of the unit cell. It has unit cell vectors a≠b≠c and interaxial angles α=γ=90°≠β.
Simple or primitive orthorhombic lattice (orthorhombic-P) has one lattice point at the each corner of the unit cell. It has unit cell vectors a≠b≠c and interaxial angles α=β=γ=90°.
Simple or primitive tetragonal lattice (tetragonal-P) has one lattice point at the each corner of the unit cell. It has unit cell vectors a=b≠c and interaxial angles α=β=γ=90°.
Smoke is a fine suspension of solid particles in a gas. In general smoke particles range downward from about 5 μm in diameter to less than 01 μm in diameter. Smoke generally refers to a visible mixture of products given off by the incomplete combustion of an organic substance such as wood, coal, fuel oil etc. This airborne mixture general contains small particles (dusts) of carbon, hydrocarbons, ash etc. as well as vapors such as carbon monoxide, carbon dioxide, and water vapor.
When a light ray comes on a boundary between two transparent media, it will be partly reflected and partly refracted. Both rays, reflected and refracted ray, lay in the plane of incidence. The angle of reflection is equal to the angle of incidence. The angle of refraction (Θ2) is related to the angle of incidence (Θ1) via Snell’s law:
where n1 and n2 are dimensionless constants - indexes of refraction of the two media.
Sols are dispersions of small solid particles in a liquid. The particles may be macromolecules or may be clusters of small molecules. Lyophobic sols are those in which there is no affinity between the dispersed phase and the liquid (e.g. silver chloride dispersed in water). Lyophobic sols are inherently unstable, in time the particles aggregate, and form a precipitate. Lyiophilic sols, on the other hand, are more like true solutions in which the solute molecules are large and have an affinity for the solvent (e.g. starch in water). Association colloids are systems in which the dispersed phase consists of clusters of molecules that have lyophobic and lyophilic parts (e.g. soap in water).
Generalic, Eni. "S.t.p.." Croatian-English Chemistry Dictionary & Glossary. 29 June 2022. KTF-Split. {Date of access}. <https://glossary.periodni.com>.
Glossary
Periodic Table
