CHEMISTRY GLOSSARY

lead    →   olovo

Lead has been known since ancient times. The origin of the name comes from the Latin word plumbum meaning liquid silver. It is very soft, highly malleable and ductile, blue-white shiny metal. Tarnishes in moist air; stable in oxygen and water. Dissolves in nitric acid. Compounds toxic by inhalation or ingestion. Danger of cumulative effects. Lead is found most often in ores called galena or lead sulfide (PbS). Used in solder, shielding against radiation and in batteries.

lead-acid battery    →   olovni akumulator

Lead-acid battery is a electrical storage device that uses a reversible chemical reaction to store energy. It was invented in 1859 by French physicist Gaston Planté. Lead-acid batteries are composed of a lead(IV) oxide cathode, a sponge metallic lead anode and a sulphuric acid solution electrolyte.

In charging, the electrical energy supplied to the battery is changed to chemical energy and stored. The chemical reaction during recharge is normally written:

In discharging, the chemical energy stored in the battery is changed to electrical energy. During discharge, lead sulfate (PbSO4) is formed on both the positive and negative plates. The chemical reaction during discharge is normally written:

Lead acid batteries are low cost, robust, tolerant to abuse, tried and tested. For higher power applications with intermittent loads however, they are generally too big and heavy and they suffer from a shorter cycle life.

leucine    →   leucin

Leucine is hydrophobic amino acids with aliphatic side chain. It has one additional methylene group in its side chain compared with valine. The nonpolar hydrophobic amino acids tend to cluster together within proteins, stabilizing protein structure by means of hydrophobic interactions. Leucine is an essential amino acid, which means that humans cannot synthesize it, so it must be ingested.

• Abbreviations: Leu, L
• IUPAC name: 2-amino-4-methylpentanoic acid
• Molecular formula: C₆H₁₃NO₂
• Molecular weight: 131.17 g/mol

lutetium    →   lutecij

Lutetium was discovered by Georges Urbain (France) and independently by Carl Auer von Welsbach (Austria) in 1907. The origin of the name comes from the Greek word Lutetia meaning Paris. It is silvery-white and relatively stable in air, rare earth metal. Lutetium is found with ytterbium in gadolinite and xenotime. Stable lutetium nuclides can be used as catalysts in cracking, alkylation, hydrogenation, and polymerization.

lysine    →   lizin

Lysine is an electrically charged amino acids with basic side chains. Lysine is a base, as are arginine and histidine. The amino group is highly reactive and often participates in reactions at the active centers of enzymes. Lysine plays an important role in coordinating negatively charged ligands. It is an essential amino acid, which means that humans cannot synthesize it, so it must be ingested.

• Abbreviations: Lys, K
• IUPAC name: 2,6-diaminohexanoic acid
• Molecular formula: C₆H₁₄N₂O₂
• Molecular weight: 146.19 g/mol

magnesium    →   magnezij

Magnesium was discovered by Sir Humphry Davy (England) in 1808. The origin of the name comes from the Greek word Magnesia, a district of Thessaly. It is lightweight, malleable, silvery-white metal. Burns in air with a brilliant white flame and reacts with water as temperature elevates. Can ignite in air. React violently with oxidants. Magnesium is found in large deposits in the form of magnesite, dolomite and other minerals. It is usually obtained by electrolysis of melted magnesium chloride (MgCl₂) derived from brines, wells and sea water. Used in alloys to make airplanes, missiles and other uses for light metals. Have structural properties similar to aluminium.

manganese    →   mangan

Manganese was discovered by Johann Gahn (Sweden) in 1774. The origin of the name comes from the Latin word magnes meaning magnet, or magnesia nigri meaning black magnesia (MnO₂). It is hard, brittle, grey-white metal with a pinkish tinge. Impure forms are reactive. Rusts like iron in moist air. Manganese is most abundant ores are pyrolusite (MnO₂), psilomelane [(Ba,H₂O)₂Mn₅O₁₀] and rhodochrosite (MnCO₃). Pure metal produced by mixing MnO₂ with powered Al and ignited in a furnace. Used in steel, batteries and ceramics. The steel in railroad tracks can contain as much as 1.2 % manganese. It is crucial to the effectiveness of vitamin B₁.

mercury    →   živa

Mercury has been known since ancient times. The origin of the name comes from the Latin word hydrargyrum meaning liquid silver. It is heavy, silver-white metal, liquid at ordinary temperatures. Stable in air and water. Unreactive with alkalis and most acids. Gives off poisonous vapour. Chronic cumulative effects. Mercury only rarely occurs free in nature. The chief ore is cinnabar or mercury sulfide (HgS). Used in thermometers, barometers and batteries. Also used in electrical switches and mercury-vapour lighting products.

methionine    →   metionin

Methionine is neutral amino acids with polar side chains. It is one of the two sulfur-containing amino acids. Methionine is a fairly hydrophobic amino acid and typically found buried within the interior of a protein. It can form stacking interactions with the aromatic moieties of tryptophan, phenylalanine, and tyrosine. It is an essential amino acid, which means that humans cannot synthesize it, so it must be ingested.

• Abbreviations: Met, M
• IUPAC name: 2-amino-4-methylsulfanylbutanoic acid
• Molecular formula: C₅H₁₁NO₂S
• Molecular weight: 149.21 g/mol

molybdenum    →   molibden

Molybdenum was discovered by Carl William Scheele (Sweden) in 1778. The origin of the name comes from the Greek word molybdos meaning lead. It is silvery white, very hard metal, but is softer and more ductile than tungsten. Molybdenum is found in the minerals molybdenite (MoS₂) and wulfenite (MoO₄Pb). Its alloys are used in aircraft, missiles and protective coatings in boiler plate.