CHEMISTRY GLOSSARY

azo compounds    →   azo-spojevi

Azo compounds are organic compounds containing the group -N=N- linking two other groups. They can be formed by reaction of a diazonium ion with a benzene ring.

Boudouard’s equilibrium    →   Boudouardova ravnoteža

Boudouard’s equilibrium is established when carbon dioxide reacts with carbon. Because of reactions endothermity the temperature increase shifts the reaction rightwards and the temperature reduction leftwards.

Bronsted acid    →   Bronstedova kiselina

Brøsted acid is a material that gives up hydrogen ions in a chemical reaction.

Bronsted base    →   Bronstedova baza

Brønsted base is a material that accepts hydrogen ions in a chemical reaction.

activation energy    →   energija aktivacije

Activation energy (E_a) is the energy that must be added to a system in order for a process to occur, even though the process may already be thermodynamically possible. In chemical kinetics, the activation energy is the height of the potential barrier separating the products and reactants. It determines the temperature dependence on the reaction rate.

active site    →   aktivno mjesto

Active site is a pocket or crevice on an enzyme molecule that fits reactant molecules like a hand in a glove. The active site lowers the activation energy for reaction

activity    →   aktivitet

Activity (a) is a thermodynamic function used in place of concentration in equilibrium constants for reactions involving nonideal gases and solutions. For the species i activity is defined as

where a_i is the activity of the species i, c_i is its molar concentration, and f_i is a dimensionless quantity called the activity coefficient.

calorimetry    →   kalorimetrija

Calorimetry is a measurement of the amount of heat evolved or absorbed in a chemical reaction, change of state, or formation of a solution, or any other event that includes heat transfer.

cation exchange    →   kationski izmjenjivač

Cation exchange is a cationic resin has positive ions built into its structure and therefore exchanges negative ions. In the cation exchange, the side groups are ionised acidic groups, such as (-SO₃H, -COOH, -OH) to which cations H⁺ are attached. The exchange reaction is one in which different cations in the solution displace the H⁺ from the solid.

chemical balance    →   kemijska ravnoteža

Chemical balance is a degree of reversible reaction in a closed system, when the forward and backward reaction happen at same rates and their effects annul each other, while the concentration of reactants and products stays the same.