CHEMISTRY GLOSSARY

electron volt    →   elektronvolt

Electron volt (eV) is a non-SI unit of energy used in atomic and nuclear physics, equal to approximately 1.602 177×10^-19 J. The electron volt is defined as the kinetic energy acquired by an electron upon acceleration through a potential difference of 1 V.

cyclic voltammetry    →   ciklička voltametrija

Cyclic voltammetry (CV) is an electrochemical measuring technique used for the determination of the kinetics and mechanism of electrode reactions. The potential of the working electrode is controlled (typically with a potentiostat) and the current flowing through the electrode is measured. It is a linear-weep voltammetry with the scan continued in the reverse direction at the end of the first scan. This cycle can be repeated a number of times, and is used for corrosion studies.

degree    →   stupanj

1. Degree is a unit of temperature on a specified scale. The temperatures of boiling and freezing water are: in the Fahrenheit system 212 and 32 degrees; in the Celsius system 100 and 0 (zero) degrees.

2. Degree is a unit of angular measure. A circle is divided into 360 degrees, represented by the symbol °. Degrees are each divided into 60 minutes. Each minute has 60 seconds. Symbols for degree, minute, and second for plane angle is placed after the numerical value and a no space between the numerical value and the unit symbol (α = 2°3'4").

3. In algebra, the degree of a polynomial is the highest power of the variable in the polynomial. For example, 4x³ + 3x² + x + 7 have degree 3.

electrical double layer    →   električni dvosloj

Electrical double layer is the structure of charge accumulation and charge separation that always occurs at the interface when an electrode is immersed into an electrolyte solution. The excess charge on the electrode surface is compensated by an accumulation of excess ions of the opposite charge in the solution. The amount of charge is a function of the electrode potential. This structure behaves essentially as a capacitor. There are several theoretical models that describe the structure of the double layer. The three most commonly used ones are the Helmholtz model, the Gouy-Chapman model, and the Gouy-Chapman-Stern model.

electrochemical series    →   elektrokemijski niz

Electrochemical series is a series of chemical elements arranged in order of their standard electrode potentials. The hydrogen electrode

is taken as having zero electrode potential. An electrode potential is, by definition, a reduction potential.

Elements that have a greater tendency than hydrogen to lose electrons to their solution are taken as electropositive; those that gain electrons from their solution are below hydrogen in the series and are called electronegative.

The series shows the order in which metals replace one another from their salts; electropositive metals will replace hydrogen from acids.

negative pole    →   negativan pol

Negative pole is that half-cell in electrochemical cell that has the most negative electrode potential.

overpotential    →   prenapon

Overpotential (η) is a potential that must be applied in an electrolytic cell in addition to the theoretical potential required to liberate a given substance at an electrode. The value depends on the electrode material and on the current density.

positive pole    →   pozitivni pol

Positive pole is that half-cell in the electrochemical cell which has the most positive electrode potential.

siemens    →   simens

Siemens (S) is the SI derived unit of of electrical conductance of a conductor in which a current of one ampere is produced by an electrical potential difference of one volt (S = A·V^-1 = Ω^-1). The unit was named after the German scientist Ernst Werner von Siemens (1816-1892).

toxicant    →   toksikant

Toxicant is a comparatively rarely-used term which describes any material which is potentially toxic.