CHEMISTRY GLOSSARY

equilibrium constant    →   konstanta ravnoteže

The equilibrium constant (K) was originally introduced in 1863 by Norwegian chemists C.M. Guldberg and P. Waage using the law of mass action. For a reversible chemical reaction represented by the equation

chemical equilibrium occurs when the rate of the forward reaction equals the rate of the back reaction, so that the concentrations of products and reactants reach steady-state values.

The equilibrium constant is the ratio of chemical activities of the species A, B, C, and D at equilibrium.

To a certain approximation, the activities can be replaced by concentrations.

For gas reactions, partial pressures are used rather than concentrations

The units of K_p and K_c depend on the numbers of molecules appearing in the stoichiometric equation (a, b, c, and d).

The value equilibrium constant depends on the temperature. If the forward reaction is exothermic, the equilibrium constant decreases as the temperature rises. The equilibrium constant shows the position of equilibrium. A low value of K indicates that [C] and [D] are small compared to [A] and [B]; i.e. that the back reaction predominates.

The equilibrium constant is related to Δ_rG°, the standard Gibbs free energy change in the reaction, by

neon    →   neon

Neon was discovered by Sir William Ramsay and Morris W. Travers (England) in 1898. The origin of the name comes from the Greek word neon meaning new. It is colourless, odourless inert gas. Non-reactive even with fluorine. Fourth most abundant element in the universe. Neon is obtained by liquefaction of air and separated from the other gases by fractional distillation. Primarily for lighting.

Newtonian fluid    →   Newtonski fluid

Newtonian fluid is a fluid whose viscosity does not depend on gradients in flow speed. Gases and low-molecular weight liquids are usually Newtonian fluids.

fluorine    →   fluor

Fluorine was discovered by Henri Moissan (France) in 1886. The origin of the name comes from the Latin word fluere meaning to flow. It is pale yellow to greenish gas, with an irritating pungent odour. Extremely reactive, flammable gas. Reacts violently with many materials. Toxic by inhalation or ingestion. Does not occur uncombined in nature. Fluorine is found in the minerals fluorite (CaF₂) and cryolite (Na₃AlF₆). Electrolysis of hydrofluoric acid (HF) or potassium acid fluoride (KHF₂) is the only practical method of commercial production. Used in refrigerants and other fluorocarbons. Also in toothpaste as sodium fluoride (NaF).

foam    →   pjena

Foams are dispersions of gases in liquids or solids. The gas globule may be of any size, from colloidal to macroscopic, as in soap bubbles. Bakers’ bread and sponge rubber are examples of solid foams. Typical liquid foams are those used in fire-fighting, shaving creams, etc. Foams made by mechanical incorporation of air are widely used in the food industry (e.g. whipped cream, egg white, ice cream, etc.). Foams can be stabilized by surfactants.

fossil fuel    →   fosilno gorivo

Fossil fuels (coal, oil, and natural gas) are the fuels used by man as a source of energy. They are formed from the remains of living organisms and all have a high carbon or hydrogen content. They have value as fuels on the exothermic oxidation of carbon to form carbon dioxide

and the oxidation of hydrogen to form water

fugacity    →   fugacitet

Fugacity (f) is a thermodynamic function used in place of partial pressure in reactions involving real gases and mixtures. For a component of a mixture, it is defined by

where μ is the chemical potential.

The fugacity of a gas is equal to the pressure if the gas is ideal. The fugacity of a liquid or solid is the fugacity of the vapour with which it is in equilibrium. The ratio of the fugacity to the fugacity in some standard state is the activity.

fume hood    →   digestor

Fume hood is a type of local exhaust ventilation system (engineering control). A typical fume hood is cabinet with a moveable front sash (window) made out of safety glass. Air is drawn into the hood under and through the opened sash and is exhausted through openings in the rear and top of the cabinet to a remote point such as an exhaust stack on the roof of the building. A properly used and properly functioning fume hood exhausts hazardous gases, dusts, mists, and vapors from a confined location and helps protect workers from inhalation exposure.

partial pressure    →   parcijalni tlak

Partial pressure is a pressure that one component of gas mixture would have if it were alone in the same volume and at the same temperature as the mixture is in now.

permeability    →   permeabilnost

Permeability (Latin permeare, to pass through) is a passage or diffusion of a gas, vapour, liquid, or solid through a material without physically or chemically affecting it.