CHEMISTRY GLOSSARY

paper chromatography    →   papirna kromatografija

Paper chromatography is one of the types of chromatography procedures which runs on a piece of specialized paper. It is a planar chromatography systems wherein a cellulose filter paper acts as a stationary phase on which separation of compounds occurs. The edge of the paper is immersed in a solvent, and the solvent moves up the paper by capillary action.

phenylalanine    →   fenilalanin

Phenylalanine is hydrophobic amino acids with aromatic side chain. It is quite hydrophobic and even the free amino acid is not very soluble in water. Phenylalanine is large aromatic residue that is normally found buried in the interior of a protein and is important for protein stability. It is an essential amino acid, which means that humans cannot synthesize it, so it must be ingested.

• Abbreviations: Phe, F
• IUPAC name: 2-amino-3-phenylpropanoic acid
• Molecular formula: C₉H₁₁NO₂
• Molecular weight: 165.19 g/mol

poison    →   otrov

Poisons are substance, which upon contact or being introduced into an organism, impair or prevent normal metabolic processes from taking place, thus altering the normal functioning of organs or tissues.

Poisons are molecules or material that tends to collect on a catalyst surface, blocking access to active sites or destroying their activities.

Poisons are substance that can reduce a nuclear reaction by absorbing neutrons, thereby preventing more fission. If enough poisons are present in a reactor core, the chain reaction will die out.

polydentant ligand    →   polidentantni liganad

Polydentant ligands contain more co-ordination points (can give more electron pairs) and they form complex ringlike structures (celate complexes) by replacing two or more monodentant ligands. That kind of ligand is EDTA which has 6 co-ordinational points and with metals it creates complexes, always in 1:1 ratio.

polymerization    →   polimerizacija

Polymerization is a reaction of connecting many monomers in one long molecule whereby polymers are created.

polymorphism    →   polimorfija

Polymorphism is the ability of a solid substance to crystallise into more than one different crystal structure. Different polymorphs have different arrangements of atoms within the unit cell, and this can have a profound effect on the properties of the final crystallised compound. The change that takes place between crystal structures of the same chemical compound is called polymorphic transformation.

The set of unique crystal structures a given compound may form are called polymorphs. Calcium carbonate is dimorphous (two forms), crystallizing as calcite or aragonite. Titanium dioxide is trimorphous; its three forms are brookite, anatase, and rutile. The prevailing crystal structure depends on both the temperature and the external pressure.

Iron is a metal with polymorphism structure. Each structure stable in the range of temperature, for example, when iron crystallizes at 1 538 °C it is bcc (δ-iron), at 1 394 °C the structure changes to fcc (γ-iron or austenite), and at 912 °C it again becomes bcc (α-iron or ferrite).

Polymorphism of an element is called allotropy.

polysaccharide    →   polisaharid

Polysaccharides are compounds consisting of a large number of simple sugars (monosaccharides) linked together by glycosidic bonds. When polysaccharides are composed of a single monosaccharide building block, they are termed homopolysaccharides. Heteropolysaccharides contain two or more different types of monosaccharide. Polysaccharides may have molecular weights of up to several million and are often highly branched. Since they have only the one free anomeric -OH group at the end of a very long chain, polysaccharides aren’t reducing sugars and don’t show noticeable mutarotation. The most common polysaccharides are cellulose, starch, and glycogen.

polystyrene    →   polistiren

Polystyrene is a vinyl polymer. Structurally, it is a long hydrocarbon chain, with a phenyl group attached to every other carbon atom. Polystyrene is produced by free radical vinyl polymerization, from the monomer styrene. Polystyrene or Styrofoam is used in the construction industry as insulating material and for production of containers.

potential energy    →   potencijalna energija

Potential energy (E_p) is the energy stored in a body or system as a consequence of its position, shape, or state (this includes gravitation energy, electrical energy, nuclear energy, and chemical energy). Gravitational potential energy is the energy associated with the state of separation between bodies that attracts each other via gravitational force. Elastic potential energy is the energy associated with the state of compression or extension of an elastic object. Thermal energy is associated with the random motions of atoms and molecules in a body.

redox reaction    →   redoks-reakcija

Redox reaction is an oxidation-reduction reaction is a reaction in which one or more electrons are transferred. When an atom, ion, or molecule loses one or more electrons, it is oxidised. When an atom, ion, or molecule gains one or more electrons, it is reduced.