Permanent hardness in water is hardness due to the presence of the chlorides, nitrates and sulphates of calcium and magnesium, which will not be precipitated by boiling. The lime scale can build up on the inside of the pipe restricting the flow of water or causing a blockage. This can happen in industry where hot water is used.
Hardness is defined as the concentrations of calcium and magnesium ions expressed in terms of calcium carbonate. These minerals in water can cause some everyday problems. They react with soap and produce a deposit called soap curd that remains on the skin and clothes and, because it is insoluble and sticky, cannot be removed by rinsing.
Hard water may also shorten the life of plumbing and water heaters. When water containing calcium carbonate is heated, a hard scale is formed that can plug pipes and coat heating elements. Scale is also a poor heat conductor. With increased deposits on the unit, heat is not transmitted to the water fast enough and overheating of the metal causes failure. Build-up of deposits will also reduce the efficiency of the heating unit, increasing the cost of fuel.
There are two types of water hardness, temporary and permanent.
Temporary Hardness is due to the bicarbonate ion, HCO3-, being present in the water. This type of hardness can be removed by boiling the water to expel the CO2, as indicated by the following equation:
Permanent hardness is due to calcium and magnesium nitrates, sulphates, and chlorides etc. This type of hardness cannot be eliminated by boiling.
Water supply classification | |
---|---|
Hardness | Concentration of Calcium carbonate (mg/L) |
Soft Water | 0 to 75 |
Medium Hard Water | 75 to 150 |
Hard Water | 150 to 300 |
Very Hard Water | over 300 |
Water softeners are substances which help remove constant water hardness. It reacts with calcium and magnesium salts, creating compounds that do not react with soap.
Temporary Hardness is due to the bicarbonate ion, HCO3-, being present in the water. It can be removed by water reboiling, whereby white solid emerges calcium carbonate that is limescale.
Brinell hardness is a scale for measuring the hardness of metals introduced around 1900 by Swedish metallurgist Johan Brinell (1849-1925). A small chromium steel ball is pressed into the surface of the metal by a load of known weight. The loading force is in the range of 300 N to 30 000 N. The ratio of the mass of the load in kilograms to the area of the depression formed in square millimetres is the Brinell Hardness Number.
Crystal water is water contained in certain salt crystals. It can be removed by heating. Crystals that contain crystal water are called hydrated and their salts hydrates.
The proportions of the major constituents of ocean water are almost constant throughout the world. Salinity (total salt content) and the concentrations of individual chemical constituents in sea wateris given the units psu (practical salinity units). For most purposes one can assume that the new unit, psu, and the older unit, ‰, are synonymous.
The average composition of the ocean water is as shown on the following table.
Constituent | Percentage of total salt |
---|---|
Chlorine | 55.3 % |
Sodium | 30.8 % |
Magnesium | 3.7 % |
Sulphur | 2.6 % |
Calcium | 1.2 % |
Potassium | 1.1 % |
Mineral water is a groundwater that rises to the surface through a natural opening in the earth or rock and contains a relatively high concentration of mineral ions and trace of elements which can be radioactive or thermal.
Deionised water is water from which ionic salts have been removed by ion-exchange. It is used for many purposes as an alternative to distilled water.
Type of water | Conductivity / µScm-1 |
---|---|
Ultrapure water | 0.05 |
Distilled water | 0.5 |
Tap water | 50 |
Ocean water | 50 000 |
Non-water solution is a solution in which the solvent is not a water (usualy non-polar).
Generalic, Eni. "Permanent hardness in water." Croatian-English Chemistry Dictionary & Glossary. 29 June 2022. KTF-Split. 3 Apr. 2025. <https://glossary.periodni.com>.
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