CHEMISTRY GLOSSARY

frequency    →   frekvencija

Frequency (ν) is the number of cycles of a periodic phenomenon divided by time. Hertz (Hz) is the SI derived unit, with a special name, for frequency, equal to s^-1. It was named after the German scientist Heinrich Hertza (1857-1894).

acetal    →   acetal

Acetals are organic compounds having the structure R₂C(OR’)₂ (R’ ≠ H). They are organic compounds formed by addition of alcohol molecules to aldehyde or ketone molecules. Originally, the term was confined to derivatives of aldehydes (one R = H), but it now applies equally to derivatives of ketones (neither R = H ). Mixed acetals have different R’ groups. The formation of acetals is reversible; acetals can be hydrolysed back to aldehydes (ketone) in acidic solutions.

Acetal, 1,1-diethoxyethane (CH₃CH(OC₂H₅)₂), is an organic compound, pleasant smelling, formed by addition of ethyl alcohol to ethanal (acetaldehyde). It is used as a solvent and in synthetic organic chemistry.

acid-base titration    →   kiselo-bazna titracija

Acid-base titration is an analytical technique in volumetric analysis, where an acid of known concentration is used to neutralise a known volume of a base, and the observed volume of the acid required is used to determine the unknown concentration of the base. An acid-base indicator is used to determine the end-point of the titration.

actinides    →   aktinoidi

Actinides (actinons or actinoids) are the fourteen elements from thorium to lawrencium inclusive, which follow actinium in the periodic table. The position of actinium is somewhat equivocal and, although not itself an actinide, it is often included with them for comparative purpose. The series includes the following elements: thorium (Th), protactinium (Pa), uranium (U), neptunium (Np), plutonium (Pu), amercium (Am), curium (Cm), berkelium (Bk), californium (Cf), einsteinium (Es), fermium (Fm), mendelevium (Md), nobelium (No) and lawrencium (Lr). Every known isotope of the actinide elements is radioactive. Traces of Pa, Np and Pu are consequently found, but only Th and U occur naturally to any useful extent.

harmonic motion    →   harmoničko gibanje

Harmonic motion is caused by restoring force, acting on a body that is displaced from its equilibrium position. This force tries to put the body back in equilibrium. Usual examples are the motion of a body attached to elastic spring (see: Hooke’s law) and the motion of mathematical pendulum. The body undergoes periodic motion around the equilibrium point.

hertz    →   herc

Hertz (Hz) is the SI derived unit, with a special name, for frequency. The hertz is the frequency of a periodic phenomenon of which the period is one second (Hz = 1 s^-1). It was named after the German scientist Heinrich Hertza (1857 - 1894).

lanthanides contraction    →   kontrakcija lantanoida

Lanthanides contraction is a reduction of metal and ion diameters from lanthanum to lutetium and it is caused by a core charge growth inside the same shell. Elements which in the periodic system of elements come after lanthanides have, because of lanthanides contraction, smaller diameter than they should have according to their position in the periodic system of elements.

activation energy    →   energija aktivacije

Activation energy (E_a) is the energy that must be added to a system in order for a process to occur, even though the process may already be thermodynamically possible. In chemical kinetics, the activation energy is the height of the potential barrier separating the products and reactants. It determines the temperature dependence on the reaction rate.

active site    →   aktivno mjesto

Active site is a pocket or crevice on an enzyme molecule that fits reactant molecules like a hand in a glove. The active site lowers the activation energy for reaction

adenosine triphosphate    →   adenozin trifosfat

Adenosine triphosphate (ATP) is nucleotide that is of fundamental importance as a carrier of chemical energy in all living organisms. It consists of adenin linked to D-ribose).