CHEMISTRY GLOSSARY

propagation    →   propagacija

Propagation is the step in a polymerization mechanism, where new monomer molecules are added to the growing polymer chain in the free radical process.

protein    →   bjelančevina

Proteins are natural organic compounds of animal or herbal origin, essential in diet. They are natural polymers developed from a crowd of interconnecting monomers of amino acids, with relative molecular masses amounting up to a few million.

equilibrium constant    →   konstanta ravnoteže

The equilibrium constant (K) was originally introduced in 1863 by Norwegian chemists C.M. Guldberg and P. Waage using the law of mass action. For a reversible chemical reaction represented by the equation

chemical equilibrium occurs when the rate of the forward reaction equals the rate of the back reaction, so that the concentrations of products and reactants reach steady-state values.

The equilibrium constant is the ratio of chemical activities of the species A, B, C, and D at equilibrium.

To a certain approximation, the activities can be replaced by concentrations.

For gas reactions, partial pressures are used rather than concentrations

The units of K_p and K_c depend on the numbers of molecules appearing in the stoichiometric equation (a, b, c, and d).

The value equilibrium constant depends on the temperature. If the forward reaction is exothermic, the equilibrium constant decreases as the temperature rises. The equilibrium constant shows the position of equilibrium. A low value of K indicates that [C] and [D] are small compared to [A] and [B]; i.e. that the back reaction predominates.

The equilibrium constant is related to Δ_rG°, the standard Gibbs free energy change in the reaction, by

radical    →   radikal

Radical is a reaction intermediate where a bond is broken and the two parts of the molecule exist carrying a single unshared electron. The radicals are normally destroyed quickly by recombination or they break into another radical and a stable molecule.

solution    →   otopina

Solutions are homogeneous mixtures of clean substances. Solutions contain two or more substances mixed in a state of molecular dispersion. Component which is found in solution in greater amount than other components is called a solvent and other components are called dissolved substances. Solution can be unsaturated, saturated and oversaturated.

solvation    →   solvatacija

Solvation is the process by which solvent molecules surround and interact with solute ions or molecules.

freon    →   freon

Freon (chlorofluorocarbon, CFC) a type of compound in which some or all of the hydrogen atoms of hydrocarbon (usually an alkane) have been replaced by chlorine and fluorine atoms. Most CFC are chemically uncreative and are stable at high temperatures. They are used as aerosol propellants, refrigerants, and solvents, and in the manufacture of rigid packaging foam. CFC because of their chemical inertness, can diffuse unchanged into the upper atmosphere. Here, photochemical reactions cause them to break down and react with ozone. For his reason, their use has been discouraged.

fructose    →   fruktoza

Fructose (fruit sugar) is a ketohexose (a six-carbon ketonic sugar), which occurs in sweet fruits and honey. Glucose and fructose have the same molecular formula, C₆H₁₂O₆, but have different structures. Pure, dry fructose is a very sweet, white, odorless, crystalline solid. Fructose is one of the sweetest of all sugars and is combined with glucose to make sucrose, or common table sugar. An older common name for fructose is levulose, after its levorotatory property of rotating plane polarized light to the left (in contrast to glucose which is dextrorotatory). The polysaccharide inulin is a polymer of fructose.

fullerene    →   fuleren

Fullerene (Buckminsterfullerene) is a form of carbon consisting of 60 carbon atoms bound together to make a roughly spherical "buckyball" (which looks rather like a soccer ball).

stereospecific reaction    →   stereospecifična reakcija

Stereospecific reactions are reactions that proceed predominantly to a single stereoisomeric product out. All metabolic conversions involving chiral molecules are stereospecific.