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Octahedron is a three-dimensional geometric figure having eight triangular sides.
Octahedral molecular geometry (square bipyramidal shape) describes the shape of compounds where six atoms or ligands are symmetrically arranged around a central atom. The sulfur hexafluoride (SF6), with six bonding pairs, is predicted and found to be a regular octahedron. Four of the attachments are positioned in a square plane with 90° bond angles. The remaining two attachments are positioned perpendicular (90°) to the square plane at opposite ends of the central atom. Molecules with an octahedral electron pair geometries have sp3d2 (or d2sp3) hybridization at the central atom.
Square planar is a molecular shape that results when there are four bonds and two lone pairs on the central atom in the molecule. An example of a square planar molecule is xenon tetrafluoride (XeF4). This molecule is made up of six equally spaced sp3d2 (or d2sp3) hybrid orbitals arranged at 90° angles. The shape of the orbitals is octahedral. Two orbitals contain lone pairs of electrons on opposite sides of the central atom. The remaining four atoms connected to the central atom give the molecule a square planar shape.
Square pyramidal is a molecular shape that results when there are five bonds and one lone pair on the central atom in the molecule. Bromine pentafluoride (BrF5) has the geometry of a square pyramid, with fluorine atoms occupying five vertices, one of which is above the plane of the other four. This molecule is made up of six equally spaced sp3d2 (or d2sp3) hybrid orbitals arranged at 90° angles. The shape of the orbitals is octahedral. Because of the high symmetry of the octahedral arrangement, all six positions are equivalent, so it does not matter in which position in the drawing we put the lone pair. The remaining four atoms connected to the central atom give the molecule a square planar shape.
Generalic, Eni. "Oktaedar." Croatian-English Chemistry Dictionary & Glossary. 29 June 2022. KTF-Split. {Date of access}. <https://glossary.periodni.com>.
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