CHEMISTRY GLOSSARY

covering power    →   prekrivna moć

Covering power is the ability of a plating solution under a set of specified plating conditions to deposit metal on the surfaces of recesses or deep holes. This term suggests an ability to cover, but not necessarily to build up, a uniform coating.

curium    →   kurij

Curium was discovered by Glenn T. Seaborg, Ralph A. James and Albert Ghiorso (USA) in 1944. Named in honour of Pierre and Marie Curie. It is silvery, malleable, synthetic radioactive metal. So radioactive it glows in the dark. Curium was made by bombarding plutonium with helium ions.

cyanide process    →   cijanidni postupak

Cyanide process is a method for separating a metal from an ore. Crushed ore is treated with cyanide ion to produce a soluble metal cyanide complex. The complex is washed out of the ore and reduced to metallic form using an active metal (usually zinc).

Born-Haber cycle    →   Born-Haberov kružni proces

Born-Haber cycle is a cycle of reactions used for calculating the lattice energies of ionic crystalline solids. For a compound MX, the lattice energy is the enthalpy of the reaction

The standard enthalpy of formation of the ionic solid is the enthalpy of the reaction

The cycle involves equating this enthalpy (which can be measured) to the sum of the enthalpies of a number of steps proceeding from the elements to the ionic solid. The steps are:

1) Atomization of the metal

2) Atomization of the nonmetal

3) Ionisation of the metal

This is obtained from the ionisation potential.

4) Ionisation of the nonmetal

This is electron affinity.

5) Formation of the ionic solids

Equation of the enthalpies gives

from which ΔH_L can be found.

boron    →   bor

Boron compounds have been known for thousands of years, but the element was not discovered until 1808 by Sir Humphry Davy (England) and independently by Joseph-Louis Gay-Lussac (France) and L. J. Thenard (France). The origin of the name comes from the Arabic word buraq and the Persian word burah meaning boraks. It is hard, brittle, lustrous black semimetal. Unreactive with oxygen, water, alkalis or acids. Combines with most metals to form borides. Boron is obtained from kernite, a kind of borax (Na₂B₄O₇·10H₂O). High purity boron is produced by electrolysis of molten potassium fluroborate and potassium chloride (KCl). Amorphous boron is used in pyrotechnic flares to provide a distinctive green color and in rockets as an igniter.

dehydrogenation    →   dehidrogenacija

Dehydrogenation is a chemical reaction in which hydrogen is removed from a compound. Dehydrogenation of organic compounds converts single carbon-carbon bonds into double bonds. It is usually affected by means of a metal catalyst or in biological systems by enzyme dehydrogenases.

derivative    →   derivat

Derivative is a compound that is derived from some other compound and usually maintains its general structure, e.g. trichlormethane (chloroform) is a derivative of methane.

einsteinium    →   einsteinij

Einsteinium was discovered by Albert Ghiorso (USA) in 1952. Named in honour of Albert Einstein (1879-1955). It is synthetic radioactive metal. Einsteinium was made by bombarding uranium with neutrons.

electrochemical potential    →   elektrokemijski potencijal

Electrochemical potential is a measure of a metal to form ions in a liquid.

electroorganic reaction    →   elektroorganske reakcije

Electroorganic reaction is an organic reaction produced in an electrolytic cell. Electroorganic reactions are used to synthesise compounds that are difficult to produce by conventional techniques. An example of an electroorganic reaction is Kolbe’s method of synthesising alkanes.