CHEMISTRY GLOSSARY

Goldschmidt process    →   Goldschmidtov postupak

Goldschmidt process (thermite process) is a method of extracting metals by reducing the oxide with aluminium powder. Practically all the metallic oxides are reducible by this method, the chief exception being the oxide of magnesium. The thermite process was developed by the German chemist Hans Goldschmidt (1861-1923) in 1893.

Goldschmidt was originally interested in producing very pure metals, but he soon realized the value in welding, a process known as Thermit welding.

Graham’s law    →   Grahamov zakon

Graham’s law is the rates at whish gases diffuse are inversely proportional to the square roots of their densities. This principle is made use of in the diffusion method of separating isotopes. The law was formulated in 1829 by British chemist Thomas Graham (1805-1869).

gravimetry    →   gravimetrija

Gravimetry is the quantitative measurement of an analyte by weighing a pure, solid form of the analyte. Since gravimetric analysis is an absolute measurement, it is the principal method for analysing and preparing primary standards.

A typical experimental procedure to determine an unknown concentration of an analyte in a solution is as follows:

- quantitatively precipitate the analyte from the solution

- collect the precipitate by filtering and wash it to remove impurities

- dry the solid in an oven to remove the solvent

- weigh the solid on an analytical balance

- calculate the analyte concentration in the original solution based on the weight of the precipitate.

selenide    →   selenid

Selenides are compounds having the structure R-Se-R (R not equal to H). They are thus selenium analogues of ethers. Also used for metal salts of H₂Se.

semimetal    →   metaloid

See Metalloid

soldering    →   lemljenje

Soldering is a process of joining metallic surfaces with solder without melting the base material.

stereospecific reaction    →   stereospecifična reakcija

Stereospecific reactions are reactions that proceed predominantly to a single stereoisomeric product out. All metabolic conversions involving chiral molecules are stereospecific.

superconductivity    →   supravodljivost

Superconductivity is the phenomenon in which certain metals, alloys, and compounds below a certain temperature, the transition point (T_c), lose electrical resistance and magnetic permeability, i.e. have infinite electrical conductivity (Meissner effect and Josephson effect).

swamp gas    →   močvarni plin

Swamp gas is a gas which develops by rottening of organic matter with no presence of air at all, e.g. at bottom of the swamp. The chief component is methane (CH₄).

tempering    →   kaljenje

Tempering is a rapid cooling of metals (often steels) from a suitable elevated temperature, thus changing its properties, e.g. steel becomes harder. This is generally accomplished by immersion in water, oil, polymer solution, or salt, although forced air is sometimes used.