CHEMISTRY GLOSSARY

vitamin    →   vitamin

The name vitamin is obtained from vital amines as it was originally thought that these substances were all amines. This is now known not to be true as vitamins have a range of structures. The body requires a small amout of vitamins, but any deficiency leads to metabolic and physical disorders.

volt    →   volt

Volt (V) is the SI derived unit of electric potential. One volt is the difference of potential between two points of an electric conductor when a current of 1 ampere flowing between those points dissipates a power of 1 watt. It was named after the Italian physicist Alessandro Volta (1745-1827).

wave-particle duality    →   valno-čestična dualnost

Wave-particle duality is an observation that electrons, photons, and other very small entities behave like particles in some experiments and like waves in others.

cerium    →   cerij

Cerium was discovered by Martin Heinrich Klaproth (Germany) and by Jöns Jacob Berzelius (Sweden) in 1803 and Wilhelm von Hisinger (Germany) in 1814. Named after the asteroid Ceres this discovered two years before the element. It is malleable, ductile, iron-grey metal. Tarnishes in air; reacts easily with water. Dissolves in acids; ignites when heated. Metal ignites and burns readily. Strong reductant. Cerium is most abundant rare earth metal. Found in many minerals like monazite sand [Ce(PO₄)]. Its oxides are used in the optics and glass-making industries. Its salts are used in the photography and textile industry. Used in high-intensity carbon lamps and as alloying agents in special metals.

Zeeman, Pieter    →   Zeeman, Pieter

Pieter Zeeman (1865-1943) was a Dutch physicist who discovered the splitting of the spectral lines of a substance when placed in a magnetic field (known as the Zeeman effect). In 1902, Zeeman and Lorentz were jointly awarded the Nobel Prize in Physics, for their, extraordinary service they rendered by their researches into the influence of magnetism upon radiation phenomenon.

Zimmermann-Reinhardt’s reagent    →   Zimmermann-Reinhardtov reagens

Zimmermann-Reinhardt’s reagent is a mixture of manganese(II) sulphate, sulphuric acid and phosphorus acid. It is used for preventing oxidation of chloride ion while titrating iron(II) ion with permanganate solution.

chemical equation    →   kemijska jednadžba

Chemical equation is a way of denoting a chemical reaction using the symbol for the participating particles (atoms, molecules, ions, etc.); for example,

The single arrow is used for an irreversible reaction; double arrows are used for reversible reactions. When reactions involve different phases, it is usual to put the phase in brackets after the symbol.

The numbers a, b, c, and d, showing the relative numbers of molecules reacting, are called the stoichiometric coefficients. The convention is that stoichiometric coefficients are positive for reactants and negative for products. If the sum of the coefficients is zero, the equation is balanced.

chlorinity    →   klorinitet

Originally chlorinity (symbol Cl) was defined as the weight of chlorine in grams per kilogram of seawater after the bromides and iodides had been replaced by chlorides. To make the definition independent of atomic weights, chlorinity is now defined as 0.3285233 times the weight of silver equivalent to all the halides.

The Mohr-Knudsen titration method served oceanographers for more than 60 years to determine salinity from chlorinity. This modification of the Mohr method uses special volumetric glassware calibrated directly in chlorinity units. The Mohr method uses potassium chromate (K₂CrO₄) as an indicator in the titration of chloride ions chloride (plus a small amount of bromide and iodide) with a silver nitrate (AgNO₃) standard solution.

The other halides present are similarly precipitated.

A problem in the Mohr titration was that silver nitrate is not well suited for a primary standard. The Danish physicist Martin Knudsen (1871-1949) suggested that a standard seawater (Eau de mer Normale or Copenhagen Normal Water) be created and distributed to oceanographic laboratories throughout the world. This water was then used to standardize the silver nitrate solutions. In this way all chlorinity determinations were referred to one and the same standard which gave great internal consistency.

The relationship between chlorinity Cl and salinity S as set forth in Knudsen's tables is

In 1962, however, a better expression for the relationship between total dissolved salts and chlorinity was found to be

Clapeyron equation    →   Clapeyronova jednadžba

Clapeyron equation (also called the Clausius-Clapeyron equation) is a relation between pressure and temperature of two phases of a pure substance that are in equilibrium,

where Δ_trsS is the difference in entropy between the phases and Δ_trsV the corresponding difference in volume.

colloid    →   koloid

Colloids are systems in which there are two or more phases, with one (the dispersed phase) distributed in the other (the continuous phase). Moreover, at least one of the phases has small dimensions, in the range between 1 nm and 1 μm (10^-9 m – 10^-6 m). Dimension, rather than the nature of the material, is characteristic. In this size range, the surface area of the particle is large with respect to its volume so that unusual phenomena occur, e.g., the particles do not settle out of the suspension by gravity and are small enough to pass through filter membranes. Macromolecules (proteins and other high polymers) are at the lower limit of this range; the upper limit is usually taken to be the point at which the particles can be resolved in an optical microscope.

Colloidal particles may be gaseous, liquid, or solid, and occur in various types of suspensions:

Sols - dispersions of small solid particles in a liquid.

Emulsions - colloidal systems in which the dispersed and continuous phases are both liquids.

Gels - colloids in which both dispersed and continuous phases have a three-dimensional network throughout the material.

Aerosols - colloidal dispersions of liquid or solid particles in a gas.

Foams - dispersions of gases in liquids or solids.