CHEMISTRY GLOSSARY

degenerate orbitals    →   degenerirane orbitale

Degenerate orbitals are orbitals with the same energy. This degeneracy can sometimes be "lifted" by external electric or magnetic fields.

electron spin    →   elektronski spin

Electron spin (s) is the quantum number, equal to 1/2, that specifies the intrinsic angular momentum of the electron.

battery    →   baterija

Battery a device that converts chemical energy to electrical energy. The process underlying the operation of a battery involves a chemical reaction in which electrons are transferred from one chemical species to another. This process is carried out in two half-reactions, one that involves the loss of electrons and one that involves their gain. The battery is an electrochemical cell divided in two half-cells, and reaction proceeds when these are connected together by an electrically conducting pathway. The passage of electrons from one half-cell to the other corresponds to an electric current. Each half-cell contains an electrode in contact with the reacting species. The electrode which passes electrons into the circuit when battery discharges is called anode and is negative terminal. The electrode which receives electrons is called cathode, and is the battery’s positive terminal. The electrical circuit is completed by an electrolyte, an electrically conducting substance placed between the two electrodes which carriers a flow of charge between them. In wet cells, the electrolyte is a liquid containing dissolved ions, whose motion generates an electrical current; in dry cells the electrolyte is basely solid, for example, a solid with mobile ions or porous solid saturated with an ionic solution.

beta particle    →   beta-čestica

Beta particle is a charged particle emitted from a radioactive atomic nucleus either natural or manufactured. The energies of beta particles range from 0 MeV to 4 MeV. They carry a single charge; if this is negative, the particle is identical with an electron; if positive, it is a positron.

An unstable atomic nucleus changes into a nucleus of the same mass number but different proton number with the emission of an electron and an antineutrino (or a positron and a neutrino)

Boltzmann constant    →   Boltzmannova konstanta

The Boltzmann constant (k or k_B) is the physical constant describing the relationship between the thermodynamic temperature and the average kinetic energy of particles in a gas. It equals the molar gas constant R divided by the Avogadro constant N_A and has the value 1.380 648 52(79)×10^-23 J/K. It is named after the Austrian physicist Ludwig Eduard Boltzmann (1844-1906).

electron volt    →   elektronvolt

Electron volt (eV) is a non-SI unit of energy used in atomic and nuclear physics, equal to approximately 1.602 177×10^-19 J. The electron volt is defined as the kinetic energy acquired by an electron upon acceleration through a potential difference of 1 V.

endothermic reaction    →   endotermna reakcija

Endothermic reactions are the ones in which heat is absorbed and are facilitated by an increase in temperature (ΔH° > 0).

If the reaction is endothermal in one direction, in the opposite direction the reaction is exothermal.

enthalpy growth    →   prirast entalpije

Enthalpy growth (ΔH) is that part of energy of system which can be translated into heat (Q) with a permanent pressure.

environment protection    →   zaštita okoliša

From Environment protection law of the Republic of Croatia: By protection of the environment, the following is ensured: complete preservation of environment quality, natural community preservation, rational usage of natural resources and energy in the most favourable way concerning the environment as a basic condition of healthy and sustainable development.

Born-Haber cycle    →   Born-Haberov kružni proces

Born-Haber cycle is a cycle of reactions used for calculating the lattice energies of ionic crystalline solids. For a compound MX, the lattice energy is the enthalpy of the reaction

The standard enthalpy of formation of the ionic solid is the enthalpy of the reaction

The cycle involves equating this enthalpy (which can be measured) to the sum of the enthalpies of a number of steps proceeding from the elements to the ionic solid. The steps are:

1) Atomization of the metal

2) Atomization of the nonmetal

3) Ionisation of the metal

This is obtained from the ionisation potential.

4) Ionisation of the nonmetal

This is electron affinity.

5) Formation of the ionic solids

Equation of the enthalpies gives

from which ΔH_L can be found.