Acid-base titration is an analytical technique in volumetric analysis, where an acid of known concentration is used to neutralise a known volume of a base, and the observed volume of the acid required is used to determine the unknown concentration of the base. An acid-base indicator is used to determine the end-point of the titration.
Lattice constants are parameters specifying the dimensions of a unit cell in a crystal lattice, specifically the lengths of the cell edges and the angles between them.
Lattice energy is the energy per ion pair required to separate completely the ions in a crystal lattice at a temperature of absolute zero.
Orthorhombic crystal system is also known as the rhombic system. Minerals of the orthorhombic crystal system are referred to three mutually perpendicular axes, each of which is of a different length than the others.
a ≠ b ≠ c
α = β = γ = 90°
Acid is a type of compound that contains hydrogen and dissociates in water to produce positive hydrogen ions. The reaction for an acid HA is commonly written:
In fact, the hydrogen ion (the proton) is solvated, and the complete reaction is:
This definition of acids comes from the Arrhenius theory. Such acids tend to be corrosive substances with a sharp taste, which turn litmus red and produce colour changes with other indicators. They are referred to as protonic acids and are classified into strong acids, which are almost completely dissociated in water, (e.g. sulphuric acid and hydrochloric acid), and weak acids, which are only partially dissociated (e.g. acetic acid and hydrogen sulphide). The strength of an acid depends on the extent to which it dissociates, and is measured by its dissociation constant.
In the Lowry-Brønsted theory of acids and bases (1923), the definition was extended to one in which an acid is a proton donor (a Brønsted acid), and a base is a proton acceptor (a Brønsted base). An important feature of the Lowry-Brønsted concept is that when an acid gives up a proton, a conjugate base is formed that is capable of accepting a proton.
Similarly, every base produces its conjugate acid as a result of accepting a proton.
For example, acetate ion is the conjugate base of acetic acid, and ammonium ion is the conjugate acid of ammonia.
As the acid of a conjugate acid/base pair becomes weaker, its conjugate base becomes stronger and vice versa.
A further extension of the idea of acids and bases was made in the Lewis theory. In this, a G. N. Lewis acid is a compound or atom that can accept a pair of electrons and a Lewis base is one that can donate an electron pair. This definition encompasses "traditional" acid-base reactions, but it also includes reactions that do not involve ions, e.g.
in which NH3 is the base (donor) and BCl3 the acid (acceptor).
Litmus paper is an unsized paper treated with litmus for the use as an acid-base indicator, in an acid it turns red, and in a base it turns blue.
Generalic, Eni. "Bazno centrirana ortorompska rešetka." Croatian-English Chemistry Dictionary & Glossary. 29 June 2022. KTF-Split. {Date of access}. <https://glossary.periodni.com>.
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