Devard’s alloy is an alloy which contains copper, aluminium and zinc (50 % Cu, 45 % Al, 5 % Zn) and is used for nitrate and nitrite reduction in order to obtain ammonia in base media.
Allomerism is the appearance of substances with different chemical composition but the same crystalline form.
Allomorphism is the existence of chemical substances with same chemical composition in two or more crystalline forms. See Polymorphism.
Allotropes are the elements which exist in two or more different forms in the same physical state. Allotropes generally differ in physical properties and may also differ in chemical activity.
Diamond, graphite and fullerenes are three allotropes of the element carbon. Graphite is a soft, black, slippery substance; by contrast, diamond is one of the hardest substances known. The different properties of the allotropes arise from their chemical structures. Diamonds typically crystallize in the cubic crystal system and consist of tetrahedrally bonded carbon atoms. Graphite crystallizes in the hexagonal system. In the fullerenes, the carbon atoms taking the form of a hollow sphere, ellipsoid, or tube.
In some cases, the allotropes are stable over a temperature range, with a definite transition point at which one changes into the other. For instance, tin has two allotropes: white (metallic) tin stable above 13.2 °C and grey (nonmetallic) tin stable below 13.2 °C.
The term allotropes may also be used to refer to the molecular forms of an element. Ozone is a chemically active triatomic allotrope of the element oxygen.
Different substances of the same elementary system are called allotropes or allotropic modifications. In the case of oxygen, there are two allotropic modifications: "normal" dioxygen (O2) and trioxygen (O3) or ozone.
Allotropy (Gr. allos, other, and tropos, manner) is the phenomenon of an element existing in two or more physical forms in the same physical state. The difference between the forms involves either crystaline structure (white, red and black phosphorus), the number of atoms in the molecule of a gas (diatomic oxygen and triatomic ozone), or the molecular structure of a liquid (liquid helium an helium II).
In some cases, the allotropes are stable over a temperature range, with a definite transition point at which one changes into the other. For instance, tin has two allotropes: white (metallic) tin stable above 13.2 °C and grey (nonmetallic) tin stable below 13.2 °C. This form allotropy is called enantiotropy. Form of allotropy, in which there is no transition temperature at which the two are in equilibrium, is called monotropy.
Allotropy does not apply to the substance existing in different physical states as, for example, when ice melts and changes from solid ice to liquid water.
Allotropy is generally restricted to describing polymorphic behaviour in elements, while polymorphism may refer to any material having multiple crystal structures.
Heusler alloys are alloys of manganese, copper, aluminium, nickel, and sometimes other metals which find important uses as permanent magnets.
Generalic, Eni. "Devard%E2%80%99s alloy." Croatian-English Chemistry Dictionary & Glossary. 29 June 2022. KTF-Split. {Date of access}. <https://glossary.periodni.com>.
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