CHEMISTRY GLOSSARY

Grignard reagent    →   Grignardov reagens

Grignard reagents are organomagnesium halides, RMgX, having a carbon- magnesium bond (or their equilibrium mixtures in solution with R₂Mg + MgX₂).

colloid ion    →   koloidni ion

Colloid ions emerge when colloid particles adsorb certain type of ion from solution and thus become charged with the same charge. The charge can also originate form a chemical reaction of colloid particle’s surface. Colloid ions formed by absorption of silver chloride particle can be show as follows:

Adsorbed layer is monomolecular (one molecule thick) and which type of ion will be formed depends upon which ions are present in a greater number in the solution in. Because of this colloid particles are charged with the same charge, mutual repelling occurs, and the colloid solution becomes stable. Colloid charge can be determined by electrophoresis.

complexometry    →   kompleksometrija

Complexometry is a volumetric analytic method which is based on titration of metal ion solutions with a substance that, combined with metal ions yields complex compounds, e.g. EDTA. The stoichiometric ratio of EDTA-metal in complexometric analyses is always 1:1, whatever the valency of the metal

composition of ocean water    →   sastav oceanske vode

The proportions of the major constituents of ocean water are almost constant throughout the world. Salinity (total salt content) and the concentrations of individual chemical constituents in sea wateris given the units psu (practical salinity units). For most purposes one can assume that the new unit, psu, and the older unit, ‰, are synonymous.

The average composition of the ocean water is as shown on the following table.

concentration    →   koncentracija

1. Group of four quantities characterizing the composition of a mixture with respect to the volume of the mixture (mass, amount, volume and number concentration).

2. Short form for amount (of substance) concentration (substance concentration in clinical chemistry).

immersion plating    →   galvaniziranje uranjanjem

Immersion plating involves depositing a metallic coating on a metal immersed in a liquid solution, without the aid of an external electric current. Also called dip plating.

isomorphism    →   izomorfija

Isomorphism is the existence of two or more substances that have the same crystal structure, so that they form solid solutions.

manganometry    →   manganometrija

Manganometry is a quantitative oxidimetric method based on measurement of potassium permanganate (KMnO₄) spent for an oxidation of the matter in question.

micelle    →   micele

Micelle is an electrically charged colloidal particle, usually organic in nature, composed of aggregates of large molecules, e.g., in soaps and surfactants. For aqueous solutions, the hydrophilic end of the molecule is on the surface of the micelle, while the hydrophobic end (often a hydrocarbon chain) points toward the centre.

conditional electrode potential    →   uvjetni elektrodni potencijal

Conditional or formal electrode potential (E°’) is equal to electrode potential (E) when overall concentrations of oxidised and reduced form in all its forms in a solution are equal to one. Conditional electrode potential includes all effects made by reactions that do not take part in the electron exchange, but lead to change of ion power, changes of pH, hydrolysis, complexing, precipitating, etc.

At 298 K (25 °C) and by converting natural (Napierian) logarithms into decimal (common, or Briggian) logarithms, Nernst’s equation for electrode potential can be written as follows: