CHEMISTRY GLOSSARY

acid    →   kiselina

Acid is a type of compound that contains hydrogen and dissociates in water to produce positive hydrogen ions. The reaction for an acid HA is commonly written:

In fact, the hydrogen ion (the proton) is solvated, and the complete reaction is:

This definition of acids comes from the Arrhenius theory. Such acids tend to be corrosive substances with a sharp taste, which turn litmus red and produce colour changes with other indicators. They are referred to as protonic acids and are classified into strong acids, which are almost completely dissociated in water, (e.g. sulphuric acid and hydrochloric acid), and weak acids, which are only partially dissociated (e.g. acetic acid and hydrogen sulphide). The strength of an acid depends on the extent to which it dissociates, and is measured by its dissociation constant.

In the Lowry-Brønsted theory of acids and bases (1923), the definition was extended to one in which an acid is a proton donor (a Brønsted acid), and a base is a proton acceptor (a Brønsted base). An important feature of the Lowry-Brønsted concept is that when an acid gives up a proton, a conjugate base is formed that is capable of accepting a proton.

Similarly, every base produces its conjugate acid as a result of accepting a proton.

For example, acetate ion is the conjugate base of acetic acid, and ammonium ion is the conjugate acid of ammonia.

As the acid of a conjugate acid/base pair becomes weaker, its conjugate base becomes stronger and vice versa.

A further extension of the idea of acids and bases was made in the Lewis theory. In this, a G. N. Lewis acid is a compound or atom that can accept a pair of electrons and a Lewis base is one that can donate an electron pair. This definition encompasses "traditional" acid-base reactions, but it also includes reactions that do not involve ions, e.g.

in which NH₃ is the base (donor) and BCl₃ the acid (acceptor).

ammonia    →   amonijak

Ammonia is a colourless gas, NH₃, with a strong pungent odour. It is easily soluble in water and alcohol. Liquid ammonia has some similarity to water as it is hydrogen bonded and has a moderate dielectric constant, which permits it to act as an ionising solvent.

antacid    →   antacid

Antacid is any mildly alkaline substance, such as sodium bicarbonate, taken internally or in water solution to neutralize excess stomach acidity.

antifreeze    →   antifriz

Antifreeze is a substance added to the liquid (usually water) in the cooling systems of internal-combustion engines to lower its freezing point so that it does not solidify at sub-zero temperatures. The commonest antifreeze is ethane- 1.2-diol (ethylene glycol).

aqueous solution    →   vodena otopina

Aqueous solutions are those solutions where water is the solvent. An aqueous solution found in an equation describing a chemical reaction is denoted by the state symbol, (aq).

beer    →   pivo

Beer is a barley and hop flavored alcoholic beverage. Beer is made by fermenting a mixture of water, barley, hops and yeast with addition of special yeast. It contains from 2 % to 5 % of alcohol. Beer is light golden yellow to reddish to almost black.

actinium    →   aktinij

Actinium was discovered by André Debierne (France) in 1899. The origin of the name comes from the Greek word aktinos meaning ray. It is heavy, silvery-white, very radioactive metal. Reacts with water. Glows in the dark. Actinium is extremely rare, found in all uranium ores. Usually obtained by treating radium with neutrons in a reactor.

activated charcoal    →   aktivni ugljen

Activated charcoal or activated carbon is charcoal that has been activated for adsorption by steaming or by heating in a vacuum. Charcoal is obtained by burning wood, nutshells, coconut husks or other materials. Charcoal becomes activated by heating it with steam to approximately 1000 °C in the absence of oxygen.

The chemical nature of amorphous carbon, combined with a high surface area makes it an ideal medium for the adsorption of organic chemicals. A single gram of such material can have 400 m² to 1 200 m² square meters of surface area. Activated charcoal is widely used to decolorize liquids, recover solvents, and remove toxins from water and air.

air stripping    →   zračni striping

Air stripping is a process for the removal of volatile organic contaminants from groundwater. The groundwater flows downward inside a tower filled with materials (the packing) over a large surface area. Air is introduced at the bottom of the tower and is forced upward past the falling water. The volatiles evaporate from the water and are collected in air filters or released to the atmosphere.

alcohol    →   alkohol

Alcohols are compounds in which a hydroxy group, -OH, is attached to a saturated carbon atom. Smaller members are water soluble, inflammable and are useful as organic solvents and fuels.