Addition reactions are normally occur with unsaturated compounds and involve the addition of one molecule (called the reactant) across the unsaturated bond (i.e. the double bond or the triple bond) of another molecule (called the substrate) to give a single product, formed by the combination of both reacting molecules.
For example, bromine adds across the double bond of ethene in an addition reaction to form dibromoethane.
Aldehydes are a broad class of organic compounds having the generic formula RCHO, and characterized by an unsaturated carbonyl group (C=O). They are formed from alcohols by either dehydrogenation or oxidation. Their chemical derivation is indicated by the name al(cohol) + dehyd(rogenation). An example of these distinct aromatic compounds is formaldehyde.
Aliphatic compounds are acyclic or cyclic, saturated or unsaturated carbon compounds, excluding aromatic compounds.
Alkanes (paraffins) are acyclic branched or unbranched hydrocarbons having the general formula CnH2n+2, and therefore consisting entirely of hydrogen atoms and saturated carbon atoms. In the systematic chemical nomenclature alkane names end in the suffix -ane. They form a homologous series (the alkane series) methane (CH4), ethane (C2H6), propane (C3H8), butane (C4H10), etc. The lower members of the series are gases; the high-molecular mass alkanes are waxy solid. Generaly the alkanes are fairly unreactive. They form haloalkanes with halogens when irradiated with ultraviolet radiation. Alkanes are present in natural gas and petroleum.
Alkenes are acyclic branched or unbranched hydrocarbons having one or more double carbon-carbon bonds in their molecules. In the systematic chemical nomenclature, alkene names end in the suffix -ene. The general formula is CnH(2n+2)-2x were x is the number of double bonds. Alkenes that have only one double bond form a homologous series: ethene (ethylene), CH2=CH2, propene, CH3CH2=CH2, etc. Alkenes typically undergo addition reactions to the double bond.
Butane is a gaseous hydrocarbon C4H10 obtained from petroleum (refinery gas or by cracking higher hydrocarbons). The fourth member of the alkane series, it has a straight chain of carbon atoms and is isomeric with 2-methylpropane, formerly called isobutene. It can easily be liquefied under pressure and is supplied into cylinders for use as a fuel gas. It is also a raw material for making buta-1, 3-diene for synthetic rubber.
Cycloalkanes are cyclic saturated hydrocarbons containing a ring of carbon atoms joined by single bonds. They have the general formula CnH2n, for example cyclohexane, C6H12. In general, they behave like the alkanes but are rather less reactive.
Alkynes (acetylenes) are acyclic branched or unbranched hydrocarbons having one or more triple carbon-carbon bond. In the systematic chemical nomenclature alkyne names end in the suffix -yne. The general formula is CnH(2n+2)-4x were x is the number of triple bonds. Alkynes that have only one triple bond form a homologous series: ethyne (acetylene), CH≡CH, propyne, CH3CH≡CH, etc. Like alkenes, alkynes undergo addition reaction.
Generalic, Eni. "Unsaturated hydrocarbon." Croatian-English Chemistry Dictionary & Glossary. 29 June 2022. KTF-Split. {Date of access}. <https://glossary.periodni.com>.
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