Acetals are organic compounds having the structure R2C(OR’)2 (R’ ≠ H). They are organic compounds formed by addition of alcohol molecules to aldehyde or ketone molecules. Originally, the term was confined to derivatives of aldehydes (one R = H), but it now applies equally to derivatives of ketones (neither R = H ). Mixed acetals have different R’ groups. The formation of acetals is reversible; acetals can be hydrolysed back to aldehydes (ketone) in acidic solutions.
Acetal, 1,1-diethoxyethane (CH3CH(OC2H5)2), is an organic compound, pleasant smelling, formed by addition of ethyl alcohol to ethanal (acetaldehyde). It is used as a solvent and in synthetic organic chemistry.
Adiabatic process is a thermodynamic process in which no heat enters or leaves the system. In general, an adiabatic change involves a fall or rise in temperature of the system.
Alkali metal is a term that refers to six elements: lithium (Li), sodium (Na), potassium (K), rubidium (Rb), caesium (Cs), and francium (Fr). These elements make up group 1 of the periodic table of elements. They all form singly charged positive ions, and are extremely reactive. They react violently with water, forming hydroxides and releasing hydrogen gas and heat. Caesium and francium are the most reactive and lithium is the least.
Allihn condenser or bulb condenser consists of an outer water jacket and the inner glass tube with a series of spherical bubbles to maximize the thermal contact with the cooling water. It is named after its inventor, the German chemist Felix Richard Allihn (1854-1915).
In radiation physics, an ideal blackbody is a theoretical object that absorbs all the radiant energy falling upon it and emits it in the form of thermal radiation. Planck’s radiation law gives the power radiated by a unit area of blackbody, and the Stefan-Boltzman law expresses the total power radiated.
1. Blanching is a heat treatment of foodstuffs to partially or completely inactivate the naturally occurring enzymes prior to freezing.
2. Blanching is a washing process for coins cleaning. The black surface layer of cupric oxide is removing by dipping the coins in hot dilute sulphuric acid (w(H2SO4) = 10 %).
Bismuth was discovered by Claude Geoffroy (France) in 1753. The origin of the name comes from the German words Weisse Masse meaning white mass; now spelled wismut and bisemutum. It is hard, brittle, steel-grey metal with a pink tint. Stable in oxygen and water. Dissolves in concentrated nitric acid. Bismuth can be found free in nature and in minerals like bismuthine (Bi2S3) and in bismuth ochre (Bi2O3) Main use is in pharmaceuticals and low melting point alloys used as fuses.
Bomb calorimeter is a type of constant-volume calorimeter used in measuring the heat of combustion of samples which can be burned in oxygen. Four essential parts are required in any bomb calorimeter:
Generalic, Eni. "Toplina nastajanja." Croatian-English Chemistry Dictionary & Glossary. 29 June 2022. KTF-Split. {Date of access}. <https://glossary.periodni.com>.
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Periodic Table