CHEMISTRY GLOSSARY

acetylene    →   acetilen

Acetylene (ethyne) is a colourless unstable gas, C₂H₂, with a characteristic sweet odour. It is lighter than air, easily soluble in acetone (propanone) and it is explosive under high pressure.

adsorption    →   adsorpcija

Adsorption is a process in which molecules of gas, of dissolved substances in liquids, or of liquids adheres in an extremely thin layer to surfaces of solid bodies with which they are in contact.

aerosol    →   aerosol

Aerosols are colloidal dispersions of liquid or solid particles in a gas, as in a mist or smoke. The commonly used aerosol sprays contain an inert propellant liquefied under pressure. The pressure of the gas causes the mixture to be released as a fine spray (aerosol) or foam (aerogel) when a valve is opened.

alloy    →   legura

Alloys are solid solutions of metal or nonmetal in metal and are prepared in order to obtain certain properties. In this way alloys can have greater hardness, corrosion resistance or some other properties gained from the metal they are composed.

Acheson process    →   Achesonov proces

Acheson process is an industrial process to synthesize graphite and silicon carbide (carborundum), named after its inventor the American chemist Edward Goodrich Acheson (1856-1931). In this process, a solid-state reaction between pure silica sand (SiO₂) and petroleum coke (C) at very high temperature (more than 2500 °C) leads to the formation of silicon carbide under the general reaction:

While studying the effects of high temperature on carborundum, Acheson had found that silicon vaporizes at about 4150 °C, leaving behind graphitic carbon.

acid    →   kiselina

Acid is a type of compound that contains hydrogen and dissociates in water to produce positive hydrogen ions. The reaction for an acid HA is commonly written:

In fact, the hydrogen ion (the proton) is solvated, and the complete reaction is:

This definition of acids comes from the Arrhenius theory. Such acids tend to be corrosive substances with a sharp taste, which turn litmus red and produce colour changes with other indicators. They are referred to as protonic acids and are classified into strong acids, which are almost completely dissociated in water, (e.g. sulphuric acid and hydrochloric acid), and weak acids, which are only partially dissociated (e.g. acetic acid and hydrogen sulphide). The strength of an acid depends on the extent to which it dissociates, and is measured by its dissociation constant.

In the Lowry-Brønsted theory of acids and bases (1923), the definition was extended to one in which an acid is a proton donor (a Brønsted acid), and a base is a proton acceptor (a Brønsted base). An important feature of the Lowry-Brønsted concept is that when an acid gives up a proton, a conjugate base is formed that is capable of accepting a proton.

Similarly, every base produces its conjugate acid as a result of accepting a proton.

For example, acetate ion is the conjugate base of acetic acid, and ammonium ion is the conjugate acid of ammonia.

As the acid of a conjugate acid/base pair becomes weaker, its conjugate base becomes stronger and vice versa.

A further extension of the idea of acids and bases was made in the Lewis theory. In this, a G. N. Lewis acid is a compound or atom that can accept a pair of electrons and a Lewis base is one that can donate an electron pair. This definition encompasses "traditional" acid-base reactions, but it also includes reactions that do not involve ions, e.g.

in which NH₃ is the base (donor) and BCl₃ the acid (acceptor).

amalgam    →   amalgam

Amalgams are metals alloyed with mercury. They can be solid or liquid, depending upon the mass ratio of thawed metal. Amalgam examples are gold/mercury, silver/mercury and copper/mercury all of which are used in dentistry.

ammonia    →   amonijak

Ammonia is a colourless gas, NH₃, with a strong pungent odour. It is easily soluble in water and alcohol. Liquid ammonia has some similarity to water as it is hydrogen bonded and has a moderate dielectric constant, which permits it to act as an ionising solvent.

activated charcoal    →   aktivni ugljen

Activated charcoal or activated carbon is charcoal that has been activated for adsorption by steaming or by heating in a vacuum. Charcoal is obtained by burning wood, nutshells, coconut husks or other materials. Charcoal becomes activated by heating it with steam to approximately 1000 °C in the absence of oxygen.

The chemical nature of amorphous carbon, combined with a high surface area makes it an ideal medium for the adsorption of organic chemicals. A single gram of such material can have 400 m² to 1 200 m² square meters of surface area. Activated charcoal is widely used to decolorize liquids, recover solvents, and remove toxins from water and air.

activity    →   aktivitet

Activity (a) is a thermodynamic function used in place of concentration in equilibrium constants for reactions involving nonideal gases and solutions. For the species i activity is defined as

where a_i is the activity of the species i, c_i is its molar concentration, and f_i is a dimensionless quantity called the activity coefficient.