CHEMISTRY GLOSSARY

temperature rating    →   temperaturno područje

Temperature rating is the maximum and minimum temperature at which the material may be used in continuous operation without loss of its basic properties. For example, temperature ratings are often quoted for electrical insulators, specifying the maximum temperature at which they provide adequate protection against electrical breakdown.

equilibrium constant    →   konstanta ravnoteže

The equilibrium constant (K) was originally introduced in 1863 by Norwegian chemists C.M. Guldberg and P. Waage using the law of mass action. For a reversible chemical reaction represented by the equation

chemical equilibrium occurs when the rate of the forward reaction equals the rate of the back reaction, so that the concentrations of products and reactants reach steady-state values.

The equilibrium constant is the ratio of chemical activities of the species A, B, C, and D at equilibrium.

To a certain approximation, the activities can be replaced by concentrations.

For gas reactions, partial pressures are used rather than concentrations

The units of K_p and K_c depend on the numbers of molecules appearing in the stoichiometric equation (a, b, c, and d).

The value equilibrium constant depends on the temperature. If the forward reaction is exothermic, the equilibrium constant decreases as the temperature rises. The equilibrium constant shows the position of equilibrium. A low value of K indicates that [C] and [D] are small compared to [A] and [B]; i.e. that the back reaction predominates.

The equilibrium constant is related to Δ_rG°, the standard Gibbs free energy change in the reaction, by

Tyndall’s effect    →   Tyndallov efekt

Tyndall’s effect occurs when light disperses on colloid particles. This phenomenon can be seen when a ray of light enters in dark room through a small hole. In the beam some dust particles of colloid dimensions can be seen sparkling.

undispersed energy    →   nedispergirana energija

Undispersed is the energy is energy of a small defined system.

unit cell    →   jedinična ćelija

Unit cell is the smallest fragment of the structure of a solid that by repetition can generate the entire structure.

vibration    →   vibracije

Vibration are small deflections of a body around equilibrium point, which usually can be described by simple harmonic motion.

vitamin    →   vitamin

The name vitamin is obtained from vital amines as it was originally thought that these substances were all amines. This is now known not to be true as vitamins have a range of structures. The body requires a small amout of vitamins, but any deficiency leads to metabolic and physical disorders.

Fajans’ rules    →   Fajansova pravila

Fajans’ rules, formulated by American chemist of Polish origin. Kazimierz Fajans (1887-1975), indicating the extent to which an ionic bond has covalent character caused by polarisation of the ions. Covalent character is more likely if:

1. the charge of the ions is high;

2. the positive ion is small or the negative ion is large;

3. the positive ion has an outer electron configuration that is not a noble- gas configuration.

ferrite    →   ferit

Ferrites are ceramic materials of the nominal formula MO·Fe₂O₃, where M is a divalent metal (Co, Mn, NI, or Zn). The ferrites show either ferrimagnetism or ferromagnetism, but are not electrical conductors, and they are used in high-frequency circuits as magnetic cores, in rectifiers on memory and record tapes, and various related uses in radio, television, radar, computers, and automatic control systems.

fission    →   fisija

Fission is a nuclear reaction in which an atomic nucleus breaks into smaller nuclei of comparable mass, releasing a large amount of energy.