CHEMISTRY GLOSSARY

thermit welding    →   termitno zavarivanje

Thermit welding is a group of welding processes in which fusion is produced by heating with superheated liquid metal resulting from a chemical reaction between a metal oxide and aluminium.

thermochemistry    →   termokemija

Termochemistry is the study of heat absorbed or released during chemical changes.

titrant    →   titrant

Titrant is the substance that quantitatively reacts with the analyte in a titration. The titrant is usually a standard solution added carefully to the analyte until the reaction is complete. The amount of analyte is calculated from the volume and concentration of titrant required for the complete reaction.

inert electrode    →   inertna elektroda

Inert electrode is an electrode that serves only as a source or sink for electrons without playing a chemical role in the electrode reaction. Precious metals, mercury, and carbon are typically used as inert electrodes. The inert nature of the electrode can sometimes be questioned. While the electrode may not take part in the reaction as a reactant or product, it still can act as an electrocatalyst.

ion-product constant    →   ionski produkt vode

The ion-product constant. For the reaction:

the equilibrium expression would be:

Note that all pure liquid terms are omitted, hence H₂O does not appear in the denominator. At 25 °C

law of conservation of mass    →   zakon o očuvanju mase

Law of conservation of mass states that no detectable gain or loss in mass occurs in chemical reactions. The state of a substance may change in a chemical reaction, for example, from a solid to a gas, but its total mass will not change. Note that the energy released (exothermic) or adsorbed (endothermic) in a chemical reaction is a result of energy transfer between atoms and their environment.

lithium    →   litij

Lithium was discovered by Johan August Arfvedson (Sweden) in 1817. The origin of the name comes from the Greek word lithos meaning stone, apparently because it was discovered from a mineral source whereas the other two elements, sodium and potassium, were discovered from plant sources. It is soft silvery-white metal. Lightest of metals. Reacts slowly with water and oxygen. Flammable. Can ignite in air. Reacts with water to give off a flammable gas. Lithium is obtained by passing electric charge through melted lithium chloride and from the silicate mineral called spodumene [LiAl(Si₂O₆)]. Used in batteries. Also for certain kinds of glass and ceramics. Some is used in lubricants.

valence shell    →   valentna ljuska

Valence shell is the shell corresponding to the highest value of principal quantum number in the atom. The valence electrons in this shell are on average farther from the nucleus than other electrons. They are often directly involved in chemical reaction.

weak acid    →   slaba kiselina

Weak acid is an acid that incompletely dissociated in aqueous solution. Acetic acid is an example of a weak acid

Nernst’s electrode potential equation    →   Nernstova jednadžba za elektrodni potencijal

For general reaction of some redox system

dependence of electrode potential of redox system upon activity of oxidised and reduced form in solution is described in Nernst’s equation for electrode potential:

where E = to electrode potential of redox system

E° = standard electrode potential of redox system

R = universal gas constant

T = thermodymical temperature

F = Faraday’s constant

z = number of electrons exchanged in redox reaction

a_O = activity of oxidised form

a_R = activity of reduced form

n = stechiometrical coefficient of oxidised form

m = stechiometrical coefficient of reduced form