CHEMISTRY GLOSSARY

allotropic modification    →   alotropska modifikacija

Different substances of the same elementary system are called allotropes or allotropic modifications. In the case of oxygen, there are two allotropic modifications: "normal" dioxygen (O₂) and trioxygen (O₃) or ozone.

allotropy    →   alotropija

Allotropy (Gr. allos, other, and tropos, manner) is the phenomenon of an element existing in two or more physical forms in the same physical state. The difference between the forms involves either crystaline structure (white, red and black phosphorus), the number of atoms in the molecule of a gas (diatomic oxygen and triatomic ozone), or the molecular structure of a liquid (liquid helium an helium II).

In some cases, the allotropes are stable over a temperature range, with a definite transition point at which one changes into the other. For instance, tin has two allotropes: white (metallic) tin stable above 13.2 °C and grey (nonmetallic) tin stable below 13.2 °C. This form allotropy is called enantiotropy. Form of allotropy, in which there is no transition temperature at which the two are in equilibrium, is called monotropy.

Allotropy does not apply to the substance existing in different physical states as, for example, when ice melts and changes from solid ice to liquid water.

Allotropy is generally restricted to describing polymorphic behaviour in elements, while polymorphism may refer to any material having multiple crystal structures.

aluminium    →   aluminij

Aluminium was discovered by Friedrich Wöhler (Germany) in 1827. The origin of the name comes from the Latin word alumen meaning alum. It is soft, lightweight, silvery-white metal. Exposed surfaces quickly form protective oxide coating. Metal reacts violently with oxidants. Third most abundant element in the earth’s crust. Aluminium is the most abundant metal to be found in the earth’s crust, but is never found free in nature. Aluminium is obtained by electrolysis from bauxite. Used for many purposes from airplanes to beverage cans. Too soft in its pure form so less than 1 % of silicon or iron is added, which hardens and strengthens it.

auxochrome    →   auksokromna grupa

Auxochrome is a group or substructure in a molecule that influences the intensity of absorption of the molecule.

Avogadro constant    →   Avogadrova konstanta

Avogadro constant (N_A or L) is the number of elementary entities in one mole of a substance.

It has the value (6.022 045±0.000 031)×10²³ mol^-1.

barytes    →   barit

Barytes is an orthorhombic mineral, form barium sulphate, BaSO₄, the chief of barium. It is usually white but my also be yellow, grey or brown. Large deposits occur in Andalusia, Spain and in the USA.

bitumen    →   bitumen

Bitumen is the final residue from petroleum fractional distillation, black tar containing free carbon.

amount concentration    →   količinska koncentracija

Amount concentration (also called molar concentration and in older literature molarity) is the amount of a given substance in a stated unit of a mixture, solution, or ore. The common unit is mole per cubic decimetre (moldm⁻³) or mole per litre (molL^-1) sometimes denoted by M.

The concentration of an atom, ion, or molecule in a solution may be symbolised by the use of square brackets, as [Ca²⁺].

amount fraction    →   količinski udio

Amount fraction, x_A, (y for gaseous mixtures) is the ratio of the amount of substance (number of moles) of substance A to the total amount of substance in a mixture.

base    →   baza

Historically, base is a substance that yields an OH - ion when it dissociates in solution, resulting in a pH>7. In the Brønsted definition, a base is a substance capable of accepting a proton in any type of reaction. The more general definition, due to G.N. Lewis, classifies any chemical species capable of donating an electron pair as a base. Typically, bases are metal oxides, hydroxides, or compounds (such as ammonia) that give hydroxide ions in aqueous solution.