CHEMISTRY GLOSSARY

standard mean ocean water    →   standardna prosječna oceanska voda

Standard mean ocean water (SMOW) is a standard sample of pure water of accurately known isotopic composition which is maintained by the International Atomic Energy Agency. It is used for precise calibration of density and isotopic composition measurements.

velocity    →   brzina

If a point-like object moves so that its position vector changes from being r_i to r_f, than the displacement Δr of object is

If a point-like object undergoes a displacement, Δr, in time Δt, its average velocity, v is defined as

The instantaneous velocity, v, is obtained from the average velocity by shrinking the time interval Δt towards zero. The average velocity approaches a limiting value, which is the velocity of a given instant:

Velocity is a vector quantity. If we plot the path of a moving particle as a curve in a coordinate system, the instantaneous velocity is always tangent to that curve.

SI unit for velocity is m s^-1.

acylaction reaction    →   reakcije aciliranja

Acylaction reaction involves the introduction of an acyl group (RCO-) into a compound. An alkyl halide is reacted with an alcohol or a carboxylic acid anhydride e.g.

The introduction of an acetyl group (CH₃CO-) is acetylation, a process used for protecting -OH groups in organic synthesis.

chain reaction    →   lančana reakcija

Chain reaction is a reaction done in three steps: initiation in which usually radicals are made which react with other molecules in stage of propagation and, when all reactants are spent, it ends by termination when all available radicals are completely spent.

Nuclear chain reaction refers to a process in which neutrons released in fission produce an additional fission in at least one further nucleus. Nuclear power plants operate by precisely controlling the rate at which nuclear reactions occur. On the other hand, nuclear weapons are specifically engineered to produce a reaction that is so fast and intense it cannot be controlled after it has started.

zero-order reaction    →   reakcija nultog reda

Zero-order reaction is a reaction for which the rate of reaction is independent of the concentration of reactants.

reversible reaction    →   reverzibilna reakcija

Reversible reaction is a chemical reaction that can proceed in both the forward and backward directions. When reversible reactions reach equilibrium the forward and reverse reactions are still happening but at the same rate, so the concentrations of reactants and products do not change. A reversible reaction is denoted by a double arrow pointing both directions in a chemical equation.

chemical reaction    →   kemijska reakcija

Chemical reaction is a change of chemical properties of substances which react with each other. By means of a chemical reaction new substances are created by bond breaking between atoms and molecules of reactants and their reuniting in a new way, thereby creating products. Chemical reactions can be shown by chemical equations.

elementary reaction    →   elementarna reakcija

Elementary reaction is a reaction that occurs in a single step. Equations for elementary reactions show the actual molecules, atoms, and ions that react on a molecular level.

endothermic reaction    →   endotermna reakcija

Endothermic reactions are the ones in which heat is absorbed and are facilitated by an increase in temperature (ΔH° > 0).

If the reaction is endothermal in one direction, in the opposite direction the reaction is exothermal.

Faradaic reaction    →   Faradejska reakcija

Faradaic reaction is a heterogeneous charge-transfer reaction occurring at the surface of an electrode.